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J Chem Phys ; 125(2): 24308, 2006 Jul 14.
Article in English | MEDLINE | ID: mdl-16848585

ABSTRACT

Effective potentials of the relativistic Breit-Pauli corrections for the 1ssigma(g) and 2psigma(u) electron states of the H(2) (+) molecular ion and the 1ssigma, 2ssigma, and 3psigma states of the antiprotonic helium atom He(+)(-)p are calculated within the Born-Oppenheimer approximation. The variational expansion with randomly chosen exponents has been used for numerical studies. The results obtained for the Breit-Pauli effective potentials are accurate up to ten significant digits for the H(2) (+) molecular ion and eight digits for the He(+)(-)p atom.

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