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1.
Chemistry ; 29(69): e202303730, 2023 Dec 11.
Article in English | MEDLINE | ID: mdl-38014989

ABSTRACT

Invited for the cover of this issue are Toshiyuki Hamura and co-workers at Kwansei Gakuin University. The image depicts solid-state generation of diarylisonaphthofuran from 1,3-diaryl-1,3-dihydronaphthofuranol and its mechanochemical Diels-Alder reaction with epoxynaphthalene. Read the full text of the article at 10.1002/chem.202302660.

2.
Chemistry ; 29(69): e202302660, 2023 Dec 11.
Article in English | MEDLINE | ID: mdl-37779416

ABSTRACT

A solid-state method was developed for generating diarylisonaphthofurans from 1,3-diaryl-1,3-dihydronaphthofuranols. The generated reactive molecules were stable in the solid state and could be stored without any extra precautions. X-ray diffraction analysis revealed a typical quinoidal structure. Furthermore, the mechanochemical Diels-Alder reaction of 1,3-diarylisonaphthofurans with epoxynaphthalenes afforded synthetically attractive diepoxypentacenes.

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