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The first A2B2-heterometal ferrimagnetic chain. Structures and magnetic properties of polymeric [Gd2Cu2]n and the corresponding monomer.
Ueki, Sohei; Kobayashi, Yasuko; Ishida, Takayuki; Nogami, Takashi.
Chem Commun (Camb) ; (41): 5223-5, 2005 Nov 07.
Article in English | MEDLINE | ID: mdl-16228042

ABSTRACT

One-dimensional polymeric complexes consisting of alternating dicopper(II) and digadolinium(III) units exhibited ferrimagnetic behavior which was ascribable to antiferromagnetic coupling across the oximate N-O bridges between the high-spin homodinuclear units.


Subject(s)
Copper/chemistry , Gadolinium/chemistry , Magnetics , Organometallic Compounds/chemistry , Crystallography, X-Ray , Models, Molecular , Molecular Structure , Temperature
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