1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 7): o2152, 2012 Jul 01.
Article
in English
| MEDLINE
| ID: mdl-22798825
ABSTRACT
The cation of the title compound, C(14)H(15)N(2)O(2) (+)·Cl(-), comprises two almost ideally planar systems, 3-nitro-phenyl (r.m.s. deviation = 0.0117â Å) and 4-methyl-phenyl (r.m.s. deviation = 0.238â Å), separated by the central C-N bond, and with their mean planes inclined to one another by 61.36â (5)°. In the crystal, hydrogen-bonded chains running along [001] are generated by connecting neighbouring mol-ecules via N-Hâ¯Cl hydrogen bonds and consolidated by C-Hâ¯Cl and C-Hâ¯O inter-actions. Within these chains, fused R(2) (1)(6) and R(3) (2)(10) ring motifs are formed. Parallel chains are further linked into a two-dimensional network parallel to (100) via C-Hâ¯O inter-actions.