Surface-enhanced optical-mid-infrared photothermal microscopy using shortened colloidal silver nanowires: a noble approach for mid-infrared surface sensing.

We propose surface-enhanced optical-mid-infrared photothermal (MIP) microscopy using highly crystalline silver nanowires, acting as a Fabry-Perot resonator, and demonstrate its applicability to enhanced mid-infrared surface sensing of thin polymer layers as thin as 20 nm.

Electrolytic synthesis of porphyrinic Zr-metal-organic frameworks with selective crystal topologies.

The thermodynamic (PCN-222) and kinetic (PCN-224) products of porphyrinic Zr-metal-organic frameworks (MOFs) were synthesized via an anodic dissolution approach for the first time. To the best of our knowledge, this is the first report of MOF polymorphs being controlled by electrolysis. The selective formation of PCN-222 requires an amorphous component to be present on the electrode during the initial reaction process.