1.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 6): o730-1, 2014 Jun 01.
Article
in English
| MEDLINE
| ID: mdl-24940297
ABSTRACT
In the title compound, C22H26N4O3S, the dihedral angle between the pyrazoloneand phenyl rings is 21.73â (4)°. The benzensulfono-hydrazide group adopts a gauche conformation about the N-N vector. The C-N-N-S torsion angle is -109.88â (13)°. The mol-ecule exists as the enamine tautomeric form (C=C-NH). An intra-molecular N-Hâ¯O=C hydrogen bond occurs. In the crystal, mol-ecules are linked by pairs of N-Hâ¯O=C hydrogen bonds, forming centrosymmetric dimers.