1.
J Org Chem
; 77(16): 7092-7, 2012 Aug 17.
Article
in English
| MEDLINE
| ID: mdl-22849794
ABSTRACT
The combination of H(3)[PW(12)O(40)]·nH(2)O (1 mol %) and Et(3)SiH led to the direct catalytic deoxygenation of propargyl alcohols, in which proper solvent selection Cl(CH(2))(2)Cl vs CF(3)CH(2)OH was the key to obtaining better product yields. Under similar conditions, the deoxygenation of allyl alcohols proceeded to give thermodynamically stable alkenes with migration of the double bonds in good yields.
Subject(s)
Alkenes/chemistry , Alkynes/chemistry , Phosphotungstic Acid/chemistry , Propanols/chemistry , Catalysis , Oxygen/chemistry , Solvents , Thermodynamics
2.
Angew Chem Int Ed Engl
; 50(51): 12197-200, 2011 Dec 16.
Article
in English
| MEDLINE
| ID: mdl-22025405
