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Chem Commun (Camb)
; 51(64): 12728-31, 2015 Aug 18.
Article
in English
| MEDLINE
| ID: mdl-26166313
ABSTRACT
The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordination compounds, as it is characterized by labile and flexible coordination bonds.