ABSTRACT
A submerged anaerobic membrane reactor (SAnMBR) was employed for comprehensive evaluation of sewage treatment at 25 °C and its performance in removal efficiency, biogas production and membrane fouling. Average 89% methanogenic degradation efficiency as well as 90%, 94% and 96% removal of total chemical oxygen demand (TCOD), biochemical oxygen demand (BOD) and nonionic surfactant were obtained, while nitrogen and phosphorus were only subjected to small removals. Results suggest that SAnMBRs can effectively decouple organic degradation and nutrients disposal, and reserve all the nitrogen and phosphorus in the effluent for further possible recovery. Small biomass yields of 0.11 g mixed liquor volatile suspended solids (MLVSS)/gCOD were achieved, coupled to excellent methane production efficiencies of 0.338 NLCH4/gCOD, making SAnMBR an attractive technology characterized by low excess sludge production and high bioenergy recovery. Batch tests revealed the SAnMBR appeared to have the potential to bear a high food-to-microorganism ratio (F/M) of 1.54 gCOD/gMLVSS without any inhibition effect, and maximum methane production rate occurred at F/M 0.7 gCOD/gMLVSS. Pore blocking dominated the membrane fouling behaviour at a relative long hydraulic retention time (HRT), i.e. >12 hours, while cake layer dominated significantly at shorter HRTs, i.e. <8 hours.
Subject(s)
Biofuels , Bioreactors , Membranes, Artificial , Sewage , Waste Disposal, Fluid/methods , Anaerobiosis , Biofouling , Biological Oxygen Demand Analysis , Biomass , Nitrogen , Phosphorus , Water Purification/instrumentation , Water Purification/methodsABSTRACT
Toilet-paper cellulose with rich but refractory carbon sources, are the main insoluble COD fractions in sewage. An anaerobic membrane bioreactor (AnMBR) was configured for sewage treatment at room temperature and its performance on methanogenic degradation of toilet paper was highlighted. The results showed, high organic removal (95%), high methane conversion (90%) and low sludge yield (0.08gVSS/gCOD) were achieved in the AnMBR. Toilet-paper cellulose was fully biodegraded without accumulation in the mixed liquor and membrane cake layer. Bioconversion efficiency of toilet paper approached 100% under a high organic loading rate (OLR) of 2.02gCOD/L/d and it could provide around 26% of total methane generation at most of OLRs. Long sludge retention time and co-digestion of insoluble/soluble COD fractions achieving mutualism of functional microorganisms, contributed to biodegradation of toilet-paper cellulose. Therefore the AnMBR successfully implemented simultaneously methanogenic bioconversion of toilet-paper cellulose and soluble COD in sewage at room temperature.