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Chem Pharm Bull (Tokyo) ; 72(2): 234-239, 2024.
Article in English | MEDLINE | ID: mdl-38417869

ABSTRACT

The first lactam-type 2-iodobenzamide catalysts, 8-iodoisoquinolinones 8 (IB-lactam) and 9 (MeO-IB-lactam), were developed. These catalysts have a conformationally rigid 6/6 bicyclic lactam structure and are more reactive than the previously reported catalysts 2-iodobenzamides 4 (IBamide) and 5 (MeO-IBamide) for the oxidation of alcohols. The lactam structure could form an efficient intramolecular I---O interaction, depending on the size of the lactam ring.


Subject(s)
Iodine , Alcohols/chemistry , Catalysis , Iodine/chemistry , Lactams , Oxidation-Reduction , Benzamides/chemistry
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