1.
J Org Chem
; 67(5): 1705-7, 2002 Mar 08.
Article
in English
| MEDLINE
| ID: mdl-11871910
ABSTRACT
Stereochemically well-defined homoallylic thioethers 3 are synthesized via Lewis acid promoted condensation reaction between chiral organosilane reagents 2 and in situ generated thionium ions. The stereochemical course of the reaction is consistent with earlier reports concerning crotylsilations of oxonium ions.
