Acid resistant functionalised magnetic nanoparticles for radionuclide and heavy metal adsorption.

Coating superparamagnetic iron oxide NPs with SiO2 has been established in order to confer stability in acidic media. Acid stability tests were carried out between pH 1 and pH 7 to determine the effectiveness of the SiO2 passivating layer to protect the magnetic Fe3O4 core. Transmission Electron Microscopy (TEM) and zeta potential measurements have shown that uncoated Fe3O4 NPs exhibit rapid agglomeration and dissolution when exposed to acidic media, moving from a zeta potential of - 26 mV to a zeta potential of + 3 mV. In contrast, the SiO2 coating of the Fe3O4 NPs shows a very high degree of stability for over 14 months and the zeta potential of these NPs remained at ∼- 39 mV throughout the acid exposure and they showed no loss in magnetisaton. Due to the use of these NPs as a potential tool for heavy metal extraction, the stability of the surface functionalisation (in this case a phosphate complex) was also assessed. With a constant zeta potential of ∼ - 29 mV for POx-SiO2@Fe3O4 NP complex, the phosphate functionality was shown to be highly stable in the acidic conditions simulating the environment of certain nuclear wastes. ATR-FTIR was conducted after acid exposure confirming that the phosphate complex on the surface of the NPs remained present. Finally, preliminary sorption experiments were carried out with Pb(II), where the NP complexes shown complete removal of the heavy metals at pH 3 and pH 5.

3D Printing Bioinspired Ceramic Composites.

Natural structural materials like bone and shell have complex, hierarchical architectures designed to control crack propagation and fracture. In modern composites there is a critical trade-off between strength and toughness. Natural structures provide blueprints to overcome this, however this approach introduces another trade-off between fine structural manipulation and manufacturing complex shapes in practical sizes and times. Here we show that robocasting can be used to build ceramic-based composite parts with a range of geometries, possessing microstructures unattainable by other production technologies. This is achieved by manipulating the rheology of ceramic pastes and the shear forces they experience during printing. To demonstrate the versatility of the approach we have fabricated highly mineralized composites with microscopic Bouligand structures that guide crack propagation and twisting in three dimensions, which we have followed using an original in-situ crack opening technique. In this way we can retain strength while enhancing toughness by using strategies taken from crustacean shells.

Properties of ceramics prepared using dry discharged waste to energy bottom ash dust.

The fine dust of incinerator bottom ash generated from dry discharge systems can be transformed into an inert material suitable for the production of hard, dense ceramics. Processing involves the addition of glass, ball milling and calcining to remove volatile components from the incinerator bottom ash. This transforms the major crystalline phases present in fine incinerator bottom ash dust from quartz (SiO(2)), calcite (CaCO(3)), gehlenite (Ca(2)Al(2)SiO(7)) and hematite (Fe(2)O(3)), to the pyroxene group minerals diopside (CaMgSi(2)O(6)), clinoenstatite (MgSi(2)O(6)), wollastonite (CaSiO(3)) together with some albite (NaAlSi(3)O(8)) and andradite (Ca(3)Fe(2)Si(3)O(12)). Processed powders show minimal leaching and can be pressed and sintered to form dense (>2.5 g cm(-3)), hard ceramics that exhibit low firing shrinkage (<7%) and zero water absorption. The research demonstrates the potential to beneficially up-cycle the fine incinerator bottom ash dust from dry discharge technology into a raw material suitable for the production of ceramic tiles that have potential for use in a range of industrial applications.

Recycling disposable cups into paper plastic composites.

The majority of disposable cups are made from paper plastic laminates (PPL) which consist of high quality cellulose fibre with a thin internal polyethylene coating. There are limited recycling options for PPLs and this has contributed to disposable cups becoming a high profile, problematic waste. In this work disposable cups have been shredded to form PPL flakes and these have been used to reinforce polypropylene to form novel paper plastic composites (PPCs). The PPL flakes and polypropylene were mixed, extruded, pelletised and injection moulded at low temperatures to prevent degradation of the cellulose fibres. The level of PPL flake addition and the use of a maleated polyolefin coupling agent to enhance interfacial adhesion have been investigated. Samples have been characterised using tensile testing, dynamic mechanical analysis (DMA) and thermogravimetric analysis. Use of a coupling agent allows composites containing 40 wt.% of PPL flakes to increase tensile strength of PP by 50% to 30 MPa. The Young modulus also increases from 1 to 2.5 GPa and the work to fracture increases by a factor of 5. The work demonstrates that PPL disposable cups have potential to be beneficially reused as reinforcement in novel polypropylene composites.