Ni-Porphyrin-based small molecule for efficient organic solar cells (>9.0%) with a high open circuit voltage of over 1.0 V and low energy loss.

A new A-π-D-π-A small molecule with a Ni-porphyrin core (MV143) has been synthesized and employed as a donor, along with PC71BM, for the fabrication of solution-processed bulk heterojunction OSCs organic solar cells. The device exhibited an overall PCE of 9.14% (JSC = 13.87 mA cm-2, VOC = 1.08 V and FF = 0.61) and a low photon energy loss of 0.52 eV.

Panchromatic ternary organic solar cells with 9.44% efficiency incorporating porphyrin-based donors.

In an effort to improve the short-circuit current and fill factor, organic solar cells have been developed with ternary blending in a single bulk heterojunction active layer. We report here several all small molecule organic solar cells based on ternary bulk heterojunction active layers. These layers consist of two small molecule porphyrin donors (MV71 and MV72), which have the same backbone but different end-capping acceptor units, and PC71BM as the acceptor. The organic solar cells showed overall power conversion efficiencies of 3.21% and 4.03% for the as-cast MV71:PC71BM and MV72:PC71BM binary active layers, respectively. However, the power conversion efficiency of the ternary active layer, i.e., MV71:MV72:PC71BM (0.2 : 0.8 : 2), was 6.72% and this is higher than the two binary active layer counterparts. The enhancement in the PCE of the ternary active layer is mainly related to the improvement in both the short-circuit current and fill factor and is related to the synergistic effect of the good miscibility of the two donors and improved hole transportation due to the slightly deeper highest occupied molecular orbital energy level of MV72 than MV71. The PCE was further improved to 9.44% with an enhanced short-circuit current and fill factor when the ternary active layer was subjected to solvent vapour annealing for 40 seconds. The ternary organic solar cells showed higher values of the incident photon to current conversion efficiency across the entire wavelength region when compared to the binary counterparts. The same donor backbone facilitates miscibility at the molecular level and the different HOMO and LUMO energy levels of the donors enable charge transport in the devices based on the ternary active layers. The increase in the power conversion efficiency after SVA treatment may be attributed to the migration of MV71 from the mixed region to the donor-acceptor (D-A) interfaces, which in turn affects the charge transfer and recombination processes and is confirmed by the impedance spectroscopy and dark current-voltage measurements.

Efficient Photoinduced Energy and Electron Transfer in ZnII -Porphyrin/Fullerene Dyads with Interchromophoric Distances up to 2.6†nm and No Wire-like Connectivity.

The dyads 1-3 made of an alkynylated ZnII -porphyrin and a bis-methanofullerene derivative connected through a copper-catalyzed azide-alkyne cycloaddition have been synthesized. The porphyrin and fullerene chromophores are separated through a bridge made of a bismethanofullerene tether linked to different spacers conjugated to the porphyrin moiety [i.e., m-phenylene (1), p-phenylene (2), di-p-phenylene-ethynylene (3)]. Compounds 1-3 exhibit relatively rigid structures with an interchromophoric separation of 1.7, 2.0, and 2.6 nm, respectively, and no face-to-face or direct through-bond conjugation. The photophysical properties of compounds 1-3 have been investigated in toluene and benzonitrile with steady-state and time-resolved techniques as well as model calculations on the Förster energy transfer. Excited-state interchromophoric electronic interactions are observed with a distinct solvent and distance dependence. The latter effect is evidenced in benzonitrile, where compounds 1 and 2 exhibit a photoinduced electron transfer in the Marcus-inverted region, with charge-separated (CS) states living for 0.44 and 0.59 µs, respectively, whereas compound 3 only undergoes energy transfer, as in apolar toluene. The quantum yield of the charge separation (φCS ) of compounds 1 and 2 in benzonitrile is ≥0.75. It is therefore demonstrated that photoinduced energy and electron transfers in porphyrin-fullerene systems with long interchromophoric distances may efficiently occur also when the bridge does not provide a wire-like conjugation and proceed through the triplet states of the chromophoric moieties.

A soluble hybrid material combining carbon nanohorns and C60.

A soluble hybrid nanomaterial that combines fullerenes and carbon nanohorns (CNHs) has been prepared and fully characterized. Electrochemical investigations revealed that the CNHs modify the electron accepting ability of C(60) in the hybrid material.

Synthesis of cyclic endiamino peptides.

Several building blocks for endiamino peptides, as well as several cyclic endiamino peptides themselves, and pyrazin-6-one, which embodies the endiamino group, were prepared. The variety of synthesized compounds shows the potential of this synthesis in the preparation of many different groups of compounds.