Structure-property-function relationships of stabilized and persistent C- and N-based triaryl radicals.

Structurally similar C- and N-based triaryl radicals are among the most commonly used structural motifs in stable, open-shell, organic molecules. The application of such species is associated with their stability, properties and structural design. This study summarizes the basic stabilization and persistence principles of C- and N-based triaryl radicals and highlights recent advances in design strategies of radicals tailored for specific applications.