Investigation on pyrolysis and incineration of chrome-tanned solid waste from tanneries for effective treatment and disposal: an experimental study.

Chrome-tanned leather solid wastes (leather finished trimmings (LFT) and chrome shavings (CS)) from tanneries were studied using pyrolysis and incineration. Detailed characterization of CS and LFT indicated higher calorific value of 15.77 MJ/kg and 19.97 MJ/kg respectively, which makes it suitable for thermal treatment. Thermal Gravimetric Analysis (TGA) of CS and LFT recorded a weight loss of 79.82% and 68.22% at 800 °C respectively. Energy-dispersive X-ray spectroscopy and scanning electron microscopy analysis for CS and LFT were also carried out. Pyrolysis of CS and LFT was carried out using a fixed bed-type pyrolysis unit at a temperature of 500 ± 10 °C for a reaction time of 30 min and three different by-products (bio-oil, biochar and pyrolytic gas) were obtained as a result of pyrolysis. From pyrolysis process, higher bio-oil yields of 52 wt.% and 49 wt.% from LFT and CS with calorific value of 28.0 and 27.8 MJ/kg respectively were obtained. The calorific values of the biochar obtained from LFT and CS were found to be 20.5 and 23.0 MJ/kg respectively. Incineration was carried out in the existing incineration facility of 150 kg/h capacity at a temperature of 1200 °C. The results of incineration process showed a higher weight reduction (93.0 wt.%) and higher concentration of gaseous emissions, revealing the need for off-gas treatment. Further, FT-IR spectra of residual ash from the incineration process revealed the occurrence of oxidation of trivalent chromium to its hexavalent form, which could be a potential raw material in the metallurgical/chemical industry for the synthesis of sodium chromate or ferrochrome alloy. Comparative experimental investigations of pyrolysis and incineration revealed that incineration could be a potential treatment and disposal option, in developing countries like India, for chrome-tanned leather solid wastes from tanneries, for producing heat energy and the residue with potential utilization viability in another industry paving a way towards circular economy.

Bio-reserves inventory-improving substrate management for anaerobic waste treatment in a fast-growing Indian urban city, Chennai.

India is one among the Asia's newly industrialized countries, in which urban centres generate large amount of municipal solid wastes due to the rapid urbanization. To demonstrate urban waste potentials for biogas production by anaerobic digestion, a comprehensive analysis on the availability of organic waste hotspots and its biogas potential for the exemplary case of Chennai, India, was undertaken. The identified hotspots and their biogas potential were plotted with Geographical Information System as thematic maps. The results of biogas potential tests revealed strong variations in the biogas potentials of individual waste streams from 240.2 to 514.2 mLN/g oDM (organic dry matter) with oDM reduction in the range of 36.4-61.5 wt.-%. Major waste generation hotspots were identified from the surveyed urban bio-reserves and the biogas potentials within an effective area of 5 km radius surrounding the hotspot were estimated. It was found that the biogas potential of individual hotspots ranged between 38.0-5938.7 m3/day. Further results revealed that the biogas potential during anaerobic co-digestion, by considering nearby bio-reserves in the effective areas of major hotspots, with and without residential organic waste, ranged between 4110.4-18-106.1 m3/day and 253.2-5969.5 m3/day, originating from 144.0-620.0 tons and 3.1-170.5 tons, respectively. Despite variations in the composition of the wastes, the Carbon/Nitrogen ratio, oDM reduction, biogas production and substrate availability were improved during co-digestion of nearby bio-reserves within the major hotspots, thereby improving the prevailing barriers in substrate management during anaerobic digestion of wastes.