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Isolation and structure of a silicocationic species with 1,3-aryl bridging between silicon atoms: a bis-silylated benzenium ion or a bridging Ph group?
Choi, Nicholas; Lickiss, Paul D; McPartlin, Mary; Masangane, Phindile C; Veneziani, Guilaine L.
Chem Commun (Camb) ; (48): 6023-5, 2005 Dec 28.
Article in English | MEDLINE | ID: mdl-16333515

ABSTRACT

Hydride abstraction from (Me3Si)3CSiMePhH by Ph3C+ affords the cation [(Me3Si)2CSiMe2-Ph-SiMe2]+, which is shown by X-ray crystallography to contain the first structurally characterised example of a Ph group bridging between two silicon atoms.


Subject(s)
Benzene/chemistry , Cross-Linking Reagents/chemistry , Phenols/chemistry , Silicon/chemistry , Cations/chemistry , Models, Molecular , Molecular Structure , Silicon/isolation & purification
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