Water disinfection by orifice-induced hydrodynamic cavitation.

Hydrodynamic Cavitation (HC) is considered as a promising water-disinfection technique. Due to the enormous complexity of the physical and chemical processes at play, research on HC reactors is usually carried out following an empirical approach. Surprisingly, past experimental studies have never been designed on dimensional-analysis principles, which makes it difficult to identify the key processes controlling the problem, isolate their effects and scale up the results from laboratory to full-scale scenarios. The present paper overcomes this issue and applies the principles of dimensional analysis to identify the major non-dimensional parameters controlling disinfection efficacy in classical HC reactors, namely orifice plates. On the basis of this analysis, it presents results from a new set of experiments, which were designed to isolate mainly the effects of the so-called cavitation number (σv). Experimental data confirm that the disinfection efficacy of orifice plates increases with decreasing σv. Finally, in order to discuss the significance of the results presented herein and frame the scope of future research, the present paper provides an overview of the drawbacks associated with dimensional analysis within the context of HC.

Thin-film-induced morphological instabilities over calcite surfaces.

Precipitation of calcium carbonate from water films generates fascinating calcite morphologies that have attracted scientific interest over past centuries. Nowadays, speleothems are no longer known only for their beauty but they are also recognized to be precious records of past climatic conditions, and research aims to unveil and understand the mechanisms responsible for their morphological evolution. In this paper, we focus on crenulations, a widely observed ripple-like instability of the the calcite-water interface that develops orthogonally to the film flow. We expand a previous work providing new insights about the chemical and physical mechanisms that drive the formation of crenulations. In particular, we demonstrate the marginal role played by carbon dioxide transport in generating crenulation patterns, which are indeed induced by the hydrodynamic response of the free surface of the water film. Furthermore, we investigate the role of different environmental parameters, such as temperature, concentration of dissolved ions and wall slope. We also assess the convective/absolute nature of the crenulation instability. Finally, the possibility of using crenulation wavelength as a proxy of past flows is briefly discussed from a theoretical point of view.