ABSTRACT
Emissions of volatile organic compounds (VOCs) from different thermoplastic polymers used in electrotechnical applications were investigated using a purge and trap procedure that involved adsorption on Tenax GR. Results were compared to those for an operating TV set monitored in a test chamber. The analyses were in both cases carried out using thermodesorption gas chromatography with mass spectrometric detection (TDS-GC/MS). Substances identified were monomers, volatile additives, or related compounds. Special attention was given to the detection of halogenated compounds. Their origin was studied using reference samples and synthetic standards.
Subject(s)
Air Pollutants/analysis , Gas Chromatography-Mass Spectrometry/methods , Polymers , Air Pollutants/chemistry , Bromine Compounds/analysis , Bromine Compounds/chemistry , Chlorine Compounds/analysis , Chlorine Compounds/chemistry , Computers , Television/instrumentation , VolatilizationABSTRACT
Recycling activities on polymeric materials are increasing and becoming more and more important in recent years. For polymers containing no flame retardants, suitable recycling strategies already exist. In order to investigate the recyclability of flame retarded polymers that contain brominated flame retardants, a number of samples were analysed as received from a recycling company. Following the identification and sorting of the samples according to type of polymers and flame retardants, material recycling was tested for the flame retarded polymers identified to occur most frequently. The reactivity of the flame retardants during the recycling procedure was studied by analysing for brominated dioxins and furans. The results demonstrate that flame retarded polymers can be recycled under certain experimental conditions.
Subject(s)
Conservation of Natural Resources , Flame Retardants/analysis , Polymers/analysis , Bromine/analysis , Dioxins/analysis , Furans/analysisABSTRACT
Combustion experiments were carried out in different house heating systems using various fuels. The emission samples and the chimney soot samples were analyzed for polychlorinated dibenzo-p-dioxins/furans (PCDD/F) and polycyclic-aromatic-hydrocarbons (PAH). The PCDD/F-concentrations in fluegases using untreated wood were in the range of 2-25 pg I-TE/m3. The combustion of paper, cartons, painted wood and wood with 2-5% PVC gave PCDD/F-concentrations from 38 to 952 pg I-TE/m3 and 380 to 2,240 ng I-TE/kg (chimney soot). The PAH-concentrations in flue gas were about 30 times higher using an old technology in relation to a new one.
Subject(s)
Air Pollution/analysis , Heating , Hydrocarbons, Aromatic/analysis , Polychlorinated Dibenzodioxins/analogs & derivatives , Coal , Environmental Monitoring , Housing , Humans , Polychlorinated Dibenzodioxins/analysis , WoodABSTRACT
5 textile finishing processes were investigated for polychlorinated dibenzo-p-dioxins/furans (PCDD/F), polybrominated dibenzo-p-dioxins/furans (PBDD/F) and mixed polychlorinated-brominated dibenzo-p-dioxins/furans (PBCDD/F). For the purpose of these investigations the complete balance--dioxins input from the raw textiles, output over the finished textiles and output through the air path--was done. In the exhaust air only small PXDD/F concentration were detected. The textiles contain before and after the process nearly the same PCDD/F-concentrations. The concentrations of PBCDD/F arises after the process. Only the chimney depositions contain higher PCDD/F-concentrations up to 1,806.1 ng I-TE/kg, PBDD/F-concentrations up to 1,572.6 ng/kg and PBCDD/F-concentrations up to 40,801.4 ng/kg.
