1.
J Org Chem
; 67(11): 3975-8, 2002 May 31.
Article
in English
| MEDLINE
| ID: mdl-12027730
ABSTRACT
The inability of the intrazeolite environment to influence the regiochemistry of addition of singlet oxygen to electron-poor olefins is reported. This divergent behavior with respect to electron-rich alkenes is rationalized with a multicomplexation model that emphasizes the importance of intrazeolite substrate-cation binding.