ABSTRACT
This study aimed to fabricate, characterize and investigate the applicability of nickel ferrite (NiFe2O4 decorated exfoliated graphite for adsorptive removal of oils and organic compounds. The exfoliated graphite/NiFe2O4 was synthesized via a simple two-step process: (i) exfoliation of the lowcost natural graphite flakes using H2O2 as oxidizing agent and H2SO4 as intercalating agent, (ii) decoration of magnetic NiFe2O4 using the acid citric-based sol-gel process. The synthesized exfoliated graphite/NiFe2O4 hybrid was then applied for the sorption of diesel oil, vegetable oil, gasoline, petroleum ether and tetrahydrofuran. Moreover, the recyclability of the used materials was investigated using either chemical or physical extraction method. Properties of the exfoliated graphite/NiFe2O4 hybrid were analysed using relevant techniques such as Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray diffraction (XRD), and Vibrating Sample Magnetometry (VSM) and N2 adsorption/desorption measurement.
ABSTRACT
Non-carbon materials are considered as the promising candidates for carbon-based catalyst support to increase the durability of proton exchange membrane fuel cells (PEMFCs). Due to the high stability and good electrical conductivity of TiO2, M-doped TiO2 (M is transition metals: Mo, Ru, V, W) is an emerging candidate for Pt nanoparticles support on the cathode side of PEMFCs. In this research, the synthesis mechanism of Ti0.7Ir0.3O2 nanostructure by the one-step hydrothermal method at low temperature was studied. We found that by only controlling the pH of the precursor solution, Ti0.7Ir0.3O2 can be synthesized with different morphology and phase selection without any formation of mixed oxides. In particular, Ti0.7Ir0.3O2 nanostructure synthesized at pH = 0 exhibited concomitant anatase, brookite, and rutile phases. The spherical particles of diameter 20-40 nm, cubic particles of 30-50 nm in side-length and rod-like particles with 70 nm in length and 20 nm in diameter represented the anatase, brookite, and rutile phases respectively. At a pH value of 1 or 2, the majority of spherical nanoparticles were homogeneous at 15-20 nm in diameter. It was observed that the electronic conductivity of novel Ti0.7Ir0.3O2 nanostructure was significantly higher than that of the undoped TiO2. Thus the promising properties of this new nanostructure open a new path to the much-needed fuel cell applications.
