ABSTRACT
In this work, a graphitic carbon nitride/gadolinium molybdate (g-C3N4/Gd2MoO6) composite manufactured glassy carbon electrode (GCE) was used to detect nitrofurazone (NFZ) at the trace level. A quick and inexpensive electrochemical sensor for NFZ analysis is described in this paper. The material structure and properties were determined by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, and transmission electron microscopy. The GCE/g-C3N4/Gd2MoO6 electrode was studied using cyclic voltammetry and amperometry. The electrocatalytic studies of the GCE/g-C3N4/Gd2MoO6 electrode showed significantly improved detection of NFZ. The electrocatalytic studies of the GCE/g-C3N4/Gd2MoO6 electrode was significantly improved for the detection of NFZ than bare GCE, GCE/g-C3N4, and GCE/Gd2MoO6 modified electrodes. The linear response and the detection limit of NFZ were 0.006 µM (S/N = 3) and 0.02-2000 µM, respectively. The electrode sensitivity was identified as 2.057 µA µM-1 cm-2 under ideal experimental conditions. The modified electrode was able to detect NFZ even when there were 500-fold as many interfering ions present. The practical applicability of the electrode was tested in a variety of water samples, with satisfactory results. Overall, the NFZ sensor demonstrated satisfactory repeatability, stability, and reproducibility. Meanwhile, it has proven to be a reliable, stable, and practical platform for the analysis of NFZ in various water samples, with acceptable recoveries.
