Fiber support prevents colloid-facilitated contamination induced by dissolution-precipitation of a calcium phosphate adsorbent.

During the adsorptive removal of hazardous metal contaminants, dissolution-precipitation of sparingly soluble adsorbents may result in the formation of toxic colloidal suspensions, triggering secondary pollution. Therefore, we studied the prevention of colloid-facilitated contamination in a model adsorption system of dicalcium phosphate dihydrate (DCPD, CaHPO4·2H2O) and Cd2+ as an adsorbent and adsorbate. Upon adding pure DCPD powder into a 500 mg L-1 Cd2+ solution of pH â‰Œ 7.0, aggregates of spheroidal Cd-bearing primary particles, within 0.040-0.95 µm size range, were generated via dissolution-precipitation. The accumulated volume of these submicron particles (10.8%) was greater than that of the submicron particles from the exposure of DCPD to deionized water (4.48%). While the Cd-carrying submicron particles, which are responsible for colloidal recontamination, appeared to form via homogeneous nucleation, their formation was suppressed using polyacrylonitrile fibers (PANFs) as supporting substrates. Thus, heterogeneous nucleation on PANFs formed hexagonal columnar microparticles of a new phase, pentacadmium dihydrogen tetrakis (phosphate) tetrahydrate (Cd5H2(PO4)4·4H2O). Together with dissolution-precipitation on the native DCPD, nucleation and growth on the PANFs accelerated the depletion of the dissolved species, reducing the degree of supersaturation along the DCPD-water interface. Although the PANFs decreased the Cd adsorption capacity to 56.7% of that of DCPD, they prevented the formation of small aggregates of Cd-bearing particles. Other sparingly soluble adsorbents can be compounded with PANF to prevent the generation of toxic colloids.

Efficient adsorptive removal of Cobalt(II) ions from water by dicalcium phosphate dihydrate.

Although the radionuclide 60Co is widely used, its presence in various effluents demands its removal to preclude environmental pollution and detrimental effects on human health. This study investigated the batch adsorption performance of a potential cobalt adsorbent, dicalcium phosphate dihydrate (DCPD), in immobilizing Co2+ from water. The influences of solution pH, contact time, initial concentration, and competing cations were examined and discussed. Stable cobalt uptake was observed at pH 4-8. The sorption kinetics showed a multi-stage uptake profile, implying that several mechanisms are involved in the adsorption process. Microscopy and structural analysis revealed that DCPD decomposes to its anhydrous form during adsorption, which explains the multistep curve over the entire adsorption period. However, the non-apatitic transformation is not exclusive to cobalt uptake. Intraparticle diffusion also contributed to the overall removal kinetics of Co2+ from water. Considering the Sips isotherm model, the maximum Co2+ adsorption capacity of DCPD was 441 mg g-1. Cobalt uptake selectivity dropped in the presence of Ca2+ ions, from 1.21 × 104 to 207 mL g-1, indicating DCPD would be more applicable in treating soft 60Co-contaminated waters. Structural analysis, elemental mapping, and qualitative analysis of solid residues confirmed that ion exchange is involved in the removal of cobalt from aqueous solutions.

Brushite-infused polyacrylonitrile nanofiber adsorbent for strontium removal from water.

The Fukushima Daiichi nuclear disaster and the decommissioning of over a hundred nuclear reactors worldwide led to the increase in the demand for efficient water treatment technologies to remove radionuclides, such as 90Sr. Brushite or dicalcium phosphate dihydrate (DCPD) is a potential adsorbent to remove strontium from water. In this study, composite poly(acrylonitrile) (PAN) nanofiber (NF) adsorbents with DCPD (PAN/DCPD) were prepared, characterized, and investigated for strontium adsorption in water. Material characterization revealed mechanically suitable, hydrophilic, and macroporous composite NF adsorbents with average fiber diameters of <500 nm. As-prepared DCPD powder exhibited a superior strontium uptake capacity of 81.7 mg g-1 at pH â‰… 10 of aqueous Sr2+ solution over its biogenic and synthetic predecessor, hydroxyapatite. Increased DCPD loading resulted in higher adsorption. Maximum Sr2+ uptake of PAN/DCPD NF with 70 wt% DCPD loading (PAN/70DCPD NF) was 146 mg g-1 considering the Sips isotherm model. Kinetic studies revealed that Sr2+ removal by PAN/DCPD NF was a chemisorption process which involved ion exchange and surface complexation. PAN/70DCPD NF as a dead-end membrane filter exhibited superior removal efficiency over pure PAN NF. The overall results of this study revealed the potential application of PAN/DCPD NF adsorbent for 90Sr removal from water.