ABSTRACT
Using scanning tunneling microscopy (STM), we followed the self-organization process of a supramolecular polymer monolayer deposited on a gold surface. During the growth of ordered domains from small to large scales, the molecule-molecule interactions were found to overrule the coupling to the substrate, causing a reorientation of the monolayer. The flexibility at the molecular level, due to reversible hydrogen bonds, was directly visualized by STM. The supramolecules were able to slide and insert between neighboring molecules, allowing the annihilation of domain boundaries and improving long range order. Large domains were found to cross monoatomic steps on the substrate without perturbation of their order.
Subject(s)
Polymers , Surface Properties , Gold/chemistry , Hydrogen Bonding , Microscopy, Scanning TunnelingABSTRACT
The semimetallic ErSi2 layer grown on Si(111) substrates provides an ideally confined 2D electron and hole gas that reflects in complex standing wave pattern at 77 K. The quasiparticles exist in a wide energy range from -800 to 300 meV without mixing with silicon bulk excitations. By comparing high resolution Fourier transform of dI/dV maps, with joint density of states calculations, we are able to determine the 2D band structure. We also clearly demonstrate that hole-hole and hole-electron quantum interferences dominate over electron-electron ones.
ABSTRACT
The process of self-assembly at multiple length scales of bis-urea substituted toluene on a Au(111) surface was studied by low temperature scanning tunneling microscopy. Pattern formation is controlled by specific hydrogen bonds between these molecules but also by significantly weaker lateral coupling between the resulting supramolecular polymers and a quasiepitaxial interlocking with the substrate. The ordered assemblies exhibit a tunnel transparency. Our experiments indicate the necessity of multiple interactions of different strengths for obtaining ordered structures with hierarchical levels of organization.
