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Chem Commun (Camb)
; 60(17): 2393-2396, 2024 Feb 22.
Article
in English
| MEDLINE
| ID: mdl-38323328
ABSTRACT
Rotaxanes can serve as scaffolds for the generation of bifunctional catalysts. We have now generated acid-base functionalized rotaxanes featuring two chiral subunits. The mechanical bond leads to increased reaction rates and also to strongly altered enantioselectivites in comparison to the non-interlocked control catalysts.