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1.
J Phys Chem B ; 114(38): 12314-8, 2010 Sep 30.
Article in English | MEDLINE | ID: mdl-20822123

ABSTRACT

The process of replacement of methane molecules in clathrate hydrate by carbon dioxide is studied experimentally. The dependence of the replacement extent on the concentration of the gas mixture coexisting with the hydrate is determined. The kinetics of the replacement is governed by two relaxation modes with a characteristic time ratio of about 10.


Subject(s)
Carbon Dioxide/chemistry , Methane/chemistry , Water/chemistry , Gases/chemistry , Kinetics , Models, Chemical , Thermodynamics
2.
Zh Vyssh Nerv Deiat Im I P Pavlova ; 56(2): 193-201, 2006.
Article in Russian | MEDLINE | ID: mdl-16756126

ABSTRACT

Changes in frequency and space parameters of the EEG coherence evoked by cognitive performance were analyzed in 13 healthy subjects and participants of the Chemobyl clean-up. In healthy subjects, the EEG coherences in the alpha and beta frequency bands were significantly increased during arithmetic count and during visuospatial performance. Each test was characterized by regionally-specific features. Chemobyl patients demonstrated a global decrease in the EEG coherence predominantly in the alpha and beta frequency bands, especially in the frontal cortical areas. Patients with various pathological EEG patterns demonstrated specific impairment of EEG parameters. In patients with a "flat" EEG pattern, the EEG coherence predominantly decreased in the frontal associative areas, especially during arithmetic calculation. In patients with a "hypersynchronous" EEG pattern, the decrease in the EEG coherence was most pronounced in the parietal associative areas, especially during the visuospatial performance. The revealed impairments of the EEG coherence reactivity may be a reflection of disorders of the intracortical and corticosubcortical interaction and can result from the remote postradiation brain atrophy, especially, of cortical structures.


Subject(s)
Brain Mapping , Cerebral Cortex/physiology , Chernobyl Nuclear Accident , Cognition/physiology , Radioactive Hazard Release , Adult , Electroencephalography , Humans , Middle Aged
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