Exposure to hazmat road accidents - Toxic release simulation and GIS-based assessment method.

Industrial demand has intensified production, utilization, and transport of hazardous materials (hazmat). As the production and use of hazardous materials are frequently carried out at different locations, accidents during the transport of hazmats constantly occur. The most critical points on the hazmat routs within inhabited urban or rural areas are centres where the population with increased vulnerability reside. This study aims to assess the exposure of people with disabilities to the impact of hazmat road accidents, in order to provide evidence-based knowledge necessary for the establishment of competent disaster preparedness procedures. A case study was developed for ammonia release from a tanker truck in the vicinity of the Institution for Children and Youth with Disabilities in Veternik, a suburban settlement of Novi Sad, Serbia. An integrated methodology for the risk assessment of the identified problem was proposed focusing on environmental and human-induced variables with a significant impact on the hazard magnitude. The simulation conducted with ALOHA (Areal Locations of Hazardous Atmospheres) confirmed assumption that the combination of high temperature and low wind speed can cause the worst-case scenario i.e. to expose a larger surface area to the influence of released ammonia. In addition, hazard maps were developed by importing the simulated area of ammonia spread into Quantum GIS (QGIS) software.

Optimization of the monitoring of landfill gas and leachate in closed methanogenic landfills.

Monitoring of the gas and leachate parameters in a closed landfill is a long-term activity defined by national legislative worldwide. Serbian Waste Disposal Law defines the monitoring of a landfill at least 30 years after its closing, but the definition of the monitoring extent (number and type of parameters) is incomplete. In order to define and clear all the uncertainties, this research focuses on process of monitoring optimization, using the closed landfill in Zrenjanin, Serbia, as the experimental model. The aim of optimization was to find representative parameters which would define the physical, chemical and biological processes in the closed methanogenic landfill and to make this process less expensive. Research included development of the five monitoring models with different number of gas and leachate parameters and each model has been processed in open source software GeoGebra which is often used for solving optimization problems. The results of optimization process identified the most favorable monitoring model which fulfills all the defined criteria not only from the point of view of mathematical analyses, but also from the point of view of environment protection. The final outcome of this research - the minimal required parameters which should be included in the landfill monitoring are precisely defined.

Results of fibre and toner flotation depending on oleic acid dosage.

The literature was reviewed with respect to deinking flotation methods with toner samples, specifically emphasizing the speciation of copy machine and laser printing, which produce an increasing quantity of paper that is difficult to recycle. Speciation here refers to the physical-chemical characteristics of the toner, which change because of the polymerization (fusion) and oxidation process, due to exposure to heat, light and oxygen (air) during the printing process. To simulate the deinking flotation, after the ideal disintegration process, samples of toner were prepared in order to provide free toner particles. Synthetic toner has iron content and the same physical-chemical features as free disintegrated printed toner particles.We report the toner (I) and fibre (Y) recovery and the brightness (B) of laboratory filter pads formed of deinked product as deinking efficiencies. The application of oleic acid as the collector in the flotation stage gives a better flotation recovery in alkaline than in acidic conditions. The highest brightness (BF = 93.66%) and flotation recoveries (I = 90, Y = 92.82%) were achieved during testing at an oleic acid concentration of 3.38·10(-6) mol l(-1), which is the lowest dose used. This makes the use of oleic acid economical and environmentally friendly.

Evaluation of key driver categories influencing sustainable waste management development with the analytic hierarchy process (AHP): Serbia example.

The problems of waste management have become increasingly complex in recent decades. The increasing amount of generated waste, adopted legislation in the field of waste management, administrative issues, economic impacts and social awareness are important drivers in achieving a sustainable waste management system. However, in practice, there are many other drivers that are often mutually in conflict. The purpose of this research is to define the precise driver and their corresponding sub-drivers, which are relevant for developing a waste management system and, on the basis of their importance, to determine which has the predominant influence on the slow development of a waste management system at the national and regional level, within the Republic of Serbia and similar countries of southeast Europe. This research presents two levels of decision making: the first is a pair-wise comparison of the drivers in relation to the goal and the second is a pair-wise comparison of the sub-drivers in relation to the driver and in relation to the goal. Results of performed analyses on the waste management drivers were integrated via the decision-making process supported by an analytic hierarchy process (AHP). The final results of this research shows that the Institutional-Administrative driver is the most important for developing a sustainable waste management system.