From mine to mind and mobiles - Lithium contamination and its risk management.

With the ever-increasing demand for lithium (Li) for portable energy storage devices, there is a global concern associated with environmental contamination of Li, via the production, use, and disposal of Li-containing products, including mobile phones and mood-stabilizing drugs. While geogenic Li is sparingly soluble, Li added to soil is one of the most mobile cations in soil, which can leach to groundwater and reach surface water through runoff. Lithium is readily taken up by plants and has relatively high plant accumulation coefficient, albeit the underlying mechanisms have not been well described. Therefore, soil contamination with Li could reach the food chain due to its mobility in surface- and ground-waters and uptake into plants. High environmental Li levels adversely affect the health of humans, animals, and plants. Lithium toxicity can be considerably managed through various remediation approaches such as immobilization using clay-like amendments and/or chelate-enhanced phytoremediation. This review integrates fundamental aspects of Li distribution and behaviour in terrestrial and aquatic environments in an effort to efficiently remediate Li-contaminated ecosystems. As research to date has not provided a clear picture of how the increased production and disposal of Li-based products adversely impact human and ecosystem health, there is an urgent need for further studies on this field.

Quality means decency-on the quality of teaching through accreditation of the course?

The term "accreditation" applies to the attempts in various fields of scientific work and administration. It refers to an acknowledgement of some particular positive (wanted) property being present in or brought about by either a procedure or technical system, an acknowledgement which is then formally issued by some authority generally accepted to be able to prove and file such statements. Bioindication & Biomonitoring (B&B) technologies are highly influenced by accreditation procedures, because both B&B technologies are often related to accreditation during the overall instrumental measurement processes applied. As an example, tuna fish used for (bio) monitoring salt water systems on pollution by Pb will be presented. Analytical measurement results from the International Measurement Evaluation Programme (IMEP 20) and additionally the construction of the university course "Integrative sustainable management: quality, environmental, health, safety and risk management (QUAR)" are reviewed in this respect. It was a serious finding by the multi-participant IMEP study that neither quality control measures nor accreditation actually ensure improved quality of measurement results, i.e. data produced by analytical laboratories. Accordingly, even though the accreditation of study curricula is often done with utmost diligence and precision, and while it is fairly important for making study curricula throughout Europe (and the World) fitting and comparable to each other to get study results produced and tested at university X also be accepted when changing to university Y, we cannot assume or take for granted that the mere protocol of accreditation will do anything positive to improve the chance to get better or "more correct" results. A single member of lab staff or professor changing to some other position might seriously compromise the turnout of some analytical lab or university course at least in the short term regardless of whether accreditation was done or not. As consequence, data obtained by B&B technologies have to be discussed and handled with the highest care to reach acceptable and scientifically sound goals of quality.

Nitrogen and metals in two regions in Central Europe: significant differences in accumulation in mosses due to land use?

The study was conducted to test the hypothesis that the regional variability of nitrogen (N) and metal accumulations in terrestrial ecosystems are due to historical and recent ways of landuse. To this end, two regions of Central Europe were selected for investigation: the Weser-Ems Region (WER) and the Euro Region Nissa (ERN). They were assumed to have land use-specific accumulation profiles. Thus, the metal and N accumulations in both regions were examined by means of geostatistically based comparative moss analysis. The sampling and chemical analysis of mosses were conducted in accordance with the convenient guidelines and methods, respectively. The spatial representativity of the sampling sites was computed by means of a land classification which was calculated for Europe by means of classification trees and GIS-techniques. The differences of deposition loads were tested for statistical significance with regard to time and space. The measurement values corroborated the decline of metal accumulation observed since the beginning of the European Metals in Mosses Surveys in 1990. The metal loads of the mosses in the ERN exceeded those in the WER significantly. The opposite holds true for the N concentrations: those in the WER were significantly higher than those in the ERN. The reduction of emissions from power plants, factories and houses was strongly correlated with the decline of deposition and bioaccumulation of metals. As proved by the European Metals in Mosses Surveys, this tendency is due to successful environmental policies. But no such success could be verified by monitoring the accumulation of N in mosses.

Dynamics of trace metals in organisms and ecosystems: prediction of metal bioconcentration in different organisms and estimation of exposure risks.

Metal ions interact with biological materials and their decomposition products by ligation (coordination complex-formation with certain moieties containing O, N, S, etc.). The extent of this interaction depends on the identities of both ligand and metal ion and can be described by some equation derived from perturbation theory. Uptake of metal ions - including highly toxic ones - from soils is controlled by a competition between root exudate components and soil organic matter (SOM) for the ions. SOM consists of a variety of potential ligands which evolve during humification towards more efficient binding (retention) of metals such as Cu, Ni, Cr but also of toxicants like U, Cd. The actual way of interaction can be inferred from stoichiometry of the involved compounds and the C/N ratio in the soil, providing predictions as to which metals will be most efficiently shuttled into green plants or fungi, respectively. The latter, selective process is crucial for closing nutrient cycles and sensitively depends on C/N ratio and the extent of "forcing" by onfalling leaf or needle litter. Therefore, analytical data on the soil can be used to predict possible risks of exposition to toxic metals also for human consumption of plant parts.