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1.
Addict Behav ; 155: 107998, 2024 08.
Article in English | MEDLINE | ID: mdl-38598904

ABSTRACT

Despite the impact of problem gambling on affected family members (AFMs), there are limited large-scale population level studies identifying the negative mental health (NMH) and positive mental health (PMH) characteristics of AFMs. Furthermore, no study has explored whether PMH characteristics are protective in the relationships between AFM status and NMH characteristics. This study involved secondary data analysis from the Third Social and Economic Impact Study of Gambling in Tasmania. Using a subsample of 1,869 adults (48.30 % male; meanage = 48.48; 4.67 % AFMs), this study aimed to explore whether: (1) AFM status is associated with NMH (depression, anxiety, panic, post-traumatic stress disorder, social anxiety, binge drinking, tobacco use, and drug use symptoms) and PMH (quality of life [QOL], personal growth/autonomy, interpersonal/social skills, coping skills) characteristics after separately controlling for sociodemographic, problem gambling severity, and other NMH characteristics; (2) PMH characteristics moderate (buffer) the relationships between AFM status and NMH characteristics; and (3) gender influences these relationships. AFM status, defined as exposure to family member gambling problems, significantly positively predicted NMH characteristics (depression, anxiety, panic, PTSD, and tobacco use symptoms) and negatively predicted QOL (physical, social) and planning coping. The strength of these relationships generally attenuated after controlling for various covariates. Gender did not moderate these relationships. Religious coping exacerbated the relationship between AFM status and panic disorder symptoms. These findings can inform the development of intervention initiatives for family members exposed to gambling problems. Future population-representative research is required using a range of affected other types, longitudinal study designs, and more comprehensive measures.


Subject(s)
Family , Gambling , Humans , Male , Female , Gambling/psychology , Gambling/epidemiology , Middle Aged , Cross-Sectional Studies , Adult , Family/psychology , Quality of Life/psychology , Tasmania/epidemiology , Adaptation, Psychological , Australia/epidemiology , Mental Health
2.
Data Brief ; 30: 105539, 2020 Jun.
Article in English | MEDLINE | ID: mdl-32373685

ABSTRACT

This article reports the data required for planning attenuation-based X-ray characterisation e.g. X-ray computed tomography (CT), of lithium-ion (Li-ion) battery cathodes. The data reported here is to accompany a co-submitted manuscript (10.1016/j.matdes.2020.108585 [1]) which compares two well-known X-ray attenuation data sources: Henke et al. and Hubbell et al., and applies methodology reported by Reiter et al. to extend this data towards the practical characterisation of prominent cathode materials. This data may be used to extend beyond the analysis reported in the accompanying manuscript, and may aid in the applications for other materials, not limited to Li-ion batteries.

3.
Trials ; 19(1): 383, 2018 Jul 16.
Article in English | MEDLINE | ID: mdl-30012192

ABSTRACT

BACKGROUND: To achieve the World Health Organization hepatitis C virus (HCV) elimination targets, it is essential to increase access to treatment. Direct-acting antiviral (DAA) treatment can be provided in primary healthcare services (PHCS), improving accessibility, and, potentially, retention in care. Here, we describe our protocol for assessing the effectiveness of providing DAAs in PHCS, and the impact on the HCV care cascade. In addition, we reflect on the challenges of conducting a model of care study during a period of unprecedented change in HCV care and treatment. METHODS: Consenting patients with HCV infection attending 13 PHCS in Australia or New Zealand are randomized to receive DAA treatment at the local tertiary institution (standard care arm), or their PHCS (intervention arm). The primary endpoint is the proportion commenced on DAAs and cured. Treatment providers at the PHCS include: hepatology nurses, primary care practitioners, or, in two sites, a specialist physician. All PHCS offer opioid substitution therapy. DISCUSSION: The Prime Study is the first real-world, randomized, model of care study exploring the impact of community provision of DAA therapy on HCV-treatment uptake and cure. Although the study has faced challenges unique to this period of time characterized by changing treatment and service delivery, the data gained will be of critical importance in shaping health service policy that enables the elimination of HCV. TRIAL REGISTRATION: ClinicalTrials.gov , ID: NCT02555475 . Registered on 15 September 2015.


Subject(s)
Antiviral Agents/therapeutic use , Community Health Services , Hepatitis C/drug therapy , Randomized Controlled Trials as Topic , Adult , Humans , Outcome Assessment, Health Care , Sample Size
4.
Sci Total Environ ; 634: 439-447, 2018 Sep 01.
Article in English | MEDLINE | ID: mdl-29631134

ABSTRACT

Reactive nitrogen (N) and phosphorus (P) inputs to surface waters modify aquatic environments, affect public health and recreation. Source controls dominate eutrophication management, whilst biological regulation of nutrients is largely neglected, although aquatic microbial organisms have huge potential to process nutrients. The stoichiometric ratio of organic carbon (OC) to N to P atoms should modulate heterotrophic pathways of aquatic nutrient processing, as high OC availability favours aquatic microbial processing. Heterotrophic microbial processing removes N by denitrification and captures N and P as organically-complexed, less eutrophying forms. With a global data synthesis, we show that the atomic ratios of bioavailable dissolved OC to either N or P in rivers with urban and agricultural land use are often distant from a "microbial optimum". This OC-deficiency relative to high availabilities of N and P likely overwhelms within-river heterotrophic processing. We propose that the capability of streams and rivers to retain N and P may be improved by active stoichiometric rebalancing. Although autotrophic OC production contributes to heterotrophic rates substantial control on nutrient processing from allochthonous OC is documented for N and an emerging field for P. Hence, rebalancing should be done by reconnecting appropriate OC sources such as wetlands and riparian forests that have become disconnected from rivers concurrent with agriculture and urbanisation. However, key knowledge gaps require research prior to the safe implementation of this approach in management: (i) to evaluate system responses to catchment inputs of dissolved OC forms and amounts relative to internal production of autotrophic dissolved OC and aquatic and terrestrial particulate OC and (ii) evaluate risk factors in anoxia-mediated P desorption with elevated OC scenarios. Still, we find stoichiometric rebalancing through reconnecting landscape beneficial OC sources has considerable potential for river management to alleviate eutrophication, improve water quality and aquatic ecosystem health, if augmenting nutrient source control.

5.
J Viral Hepat ; 25(9): 1089-1098, 2018 09.
Article in English | MEDLINE | ID: mdl-29660212

ABSTRACT

To increase access to treatment, the Australian government enabled general practitioners (GPs) to prescribe direct-acting antivirals (DAAs) to treat hepatitis C virus (HCV)-in consultation with a specialist if inexperienced in HCV management. This study describes the establishment and outcomes of a remote consultation pathway supporting GPs to treat HCV. Key stakeholders from primary and tertiary healthcare services in the Barwon South Western region developed and implemented an HCV remote consultation pathway. Pharmaceutical Benefits Schedule prescription data were used to evaluate GP DAA prescription 12 months pre-and post- pathway implementation. A retrospective review of patients referred for remote consultation for 12 months post- pathway inception was undertaken to determine the care cascade. HCV treatment initiation by GPs increased after implementation of the remote consultation pathway. In the 12-month study period, 74 GPs referred 169 people for remote consultation; 114 (67%) were approved for GP DAA treatment; 48 (28%) were referred for specialist assessment. In total, 119 (71%) patients commenced DAA; 69 were eligible for SVR12 assessment. Post-treatment HCV RNA data were available for 52 (75%) people; 37 achieved SVR12; 15 achieved SVR ranging from week 5 to 11 post-treatment. No treatment failure was detected. Collaborative development and implementation of a remote consultation pathway has engaged regional GPs in managing HCV. Follow-up post-treatment could be improved; however, no treatment failure has been documented. To eliminate HCV as a public health threat, it is vital that specialists support GPs to prescribe DAA.


Subject(s)
Antiviral Agents/therapeutic use , General Practitioners , Health Services Accessibility , Hepatitis C, Chronic/drug therapy , Patient Acceptance of Health Care , Remote Consultation/organization & administration , Remote Consultation/statistics & numerical data , Adult , Australia , Female , Humans , Male , Middle Aged , RNA, Viral/blood , Retrospective Studies , Sustained Virologic Response , Treatment Outcome
6.
Sci Total Environ ; 578: 323-336, 2017 Feb 01.
Article in English | MEDLINE | ID: mdl-27838058

ABSTRACT

It is increasingly recognised that widespread and substantial increases in Dissolved organic carbon (DOC) concentrations in remote surface, and soil, waters in recent decades are linked to declining acid deposition. Effects of rising pH and declining ionic strength on DOC solubility have been proposed as potential dominant mechanisms. However, since DOC in these systems is derived mainly from recently-fixed carbon, and since organic matter decomposition rates are considered sensitive to temperature, uncertainty persists over the extent to which other drivers that could influence DOC production. Such potential drivers include fertilisation by nitrogen (N) and global warming. We therefore ran the dynamic soil chemistry model MADOC for a range of UK soils, for which time series data are available, to consider the likely relative importance of decreased deposition of sulphate and chloride, accumulation of reactive N, and higher temperatures, on soil DOC production in different soils. Modelled patterns of DOC change generally agreed favourably with measurements collated over 10-20years, but differed markedly between sites. While the acidifying effect of sulphur deposition appeared to be the predominant control on the observed soil water DOC trends in all the soils considered other than a blanket peat, the model suggested that over the long term, the effects of nitrogen deposition on N-limited soils may have been sufficient to raise the "acid recovery DOC baseline" significantly. In contrast, reductions in non-marine chloride deposition and effects of long term warming appeared to have been relatively unimportant. The suggestion that future DOC concentrations might exceed preindustrial levels as a consequence of nitrogen pollution has important implications for drinking water catchment management and the setting and pursuit of appropriate restoration targets, but findings still require validation from reliable centennial-scale proxy records, such as those being developed using palaeolimnological techniques.

7.
Environ Sci Process Impacts ; 18(6): 677-89, 2016 Jun 15.
Article in English | MEDLINE | ID: mdl-27192431

ABSTRACT

Dissolved oxygen (DO) concentrations showed a striking pattern in a multi-year study of the River Enborne, a small river in SE England. In each of three years (2010-2012), maximum DO concentrations were attained in mid-April, preceded by a period of steadily increasing diurnal amplitudes, followed by a steady reduction in both amplitude and concentration. Flow events during the reduction period reduce DO to low concentrations until the following spring. Evidence is presented that this pattern is mainly due to benthic algal growth which is eventually suppressed by the growth of the riparian tree canopy. Nitrate and silicate concentrations are too high to inhibit the growth of either benthic algae or phytoplankton, but phosphate concentrations might have started to reduce growth if the tree canopy development had been delayed. This interpretation is supported by evidence from weekly flow cytometry measurements and analysis of the diurnal, seasonal and annual patterns of nutrient concentrations. As the tree canopy develops, the river switches from an autotrophic to a heterotrophic state. The results support the use of riparian shading to help control algal growth, and highlight the risks of reducing riparian shade.


Subject(s)
Chlorophyta/growth & development , Ecosystem , Eutrophication , Phytoplankton/growth & development , Rivers , Sunlight , Trees/growth & development , Autotrophic Processes , Conservation of Natural Resources , England , Environmental Monitoring , Heterotrophic Processes , Nitrates/analysis , Phosphates/analysis , Seasons
8.
Sci Total Environ ; 511: 608-20, 2015 Apr 01.
Article in English | MEDLINE | ID: mdl-25596349

ABSTRACT

The total reactive phosphorus (TRP) and nitrate concentrations of the River Enborne, southern England, were monitored at hourly interval between January 2010 and December 2011. The relationships between these high-frequency nutrient concentration signals and flow were used to infer changes in nutrient source and dynamics through the annual cycle and each individual storm event, by studying hysteresis patterns. TRP concentrations exhibited strong dilution patterns with increasing flow, and predominantly clockwise hysteresis through storm events. Despite the Enborne catchment being relatively rural for southern England, TRP inputs were dominated by constant, non-rain-related inputs from sewage treatment works (STW) for the majority of the year, producing the highest phosphorus concentrations through the spring-summer growing season. At higher river flows, the majority of the TRP load was derived from within-channel remobilisation of phosphorus from the bed sediment, much of which was also derived from STW inputs. Therefore, future phosphorus mitigation measures should focus on STW improvements. Agricultural diffuse TRP inputs were only evident during storms in the May of each year, probably relating to manure application to land. The nitrate concentration-flow relationship produced a series of dilution curves, indicating major inputs from groundwater and to a lesser extent STW. Significant diffuse agricultural inputs with anticlockwise hysteresis trajectories were observed during the first major storms of the winter period. The simultaneous investigation of high-frequency time series data, concentration-flow relationships and hysteresis behaviour through multiple storms for both phosphorus and nitrate offers a simple and innovative approach for providing new insights into nutrient sources and dynamics.

9.
Philos Trans A Math Phys Eng Sci ; 371(2002): 20120413, 2013 Nov 13.
Article in English | MEDLINE | ID: mdl-24080622

ABSTRACT

The catchment of the River Thames, the principal river system in southern England, provides the main water supply for London but is highly vulnerable to changes in climate, land use and population. The river is eutrophic with significant algal blooms with phosphorus assumed to be the primary chemical indicator of ecosystem health. In the Thames Basin, phosphorus is available from point sources such as wastewater treatment plants and from diffuse sources such as agriculture. In order to predict vulnerability to future change, the integrated catchments model for phosphorus (INCA-P) has been applied to the river basin and used to assess the cost-effectiveness of a range of mitigation and adaptation strategies. It is shown that scenarios of future climate and land-use change will exacerbate the water quality problems, but a range of mitigation measures can improve the situation. A cost-effectiveness study has been undertaken to compare the economic benefits of each mitigation measure and to assess the phosphorus reductions achieved. The most effective strategy is to reduce fertilizer use by 20% together with the treatment of effluent to a high standard. Such measures will reduce the instream phosphorus concentrations to close to the EU Water Framework Directive target for the Thames.

10.
Sci Total Environ ; 454-455: 230-44, 2013 Jun 01.
Article in English | MEDLINE | ID: mdl-23542675

ABSTRACT

Soluble reactive phosphorus (SRP) plays a key role in eutrophication, a global problem decreasing habitat quality and in-stream biodiversity. Mitigation strategies are required to prevent SRP fluxes from exceeding critical levels, and must be robust in the face of potential changes in climate, land use and a myriad of other influences. To establish the longevity of these strategies it is therefore crucial to consider the sensitivity of catchments to multiple future stressors. This study evaluates how the water quality and hydrology of a major river system in the UK (the River Thames) respond to alterations in climate, land use and water resource allocations, and investigates how these changes impact the relative performance of management strategies over an 80-year period. In the River Thames, the relative contributions of SRP from diffuse and point sources vary seasonally. Diffuse sources of SRP from agriculture dominate during periods of high runoff, and point sources during low flow periods. SRP concentrations rose under any future scenario which either increased a) surface runoff or b) the area of cultivated land. Under these conditions, SRP was sourced from agriculture, and the most effective single mitigation measures were those which addressed diffuse SRP sources. Conversely, where future scenarios reduced flow e.g. during winters of reservoir construction, the significance of point source inputs increased, and mitigation measures addressing these issues became more effective. In catchments with multiple point and diffuse sources of SRP, an all-encompassing effective mitigation approach is difficult to achieve with a single strategy. In order to attain maximum efficiency, multiple strategies might therefore be employed at different times and locations, to target the variable nature of dominant SRP sources and pathways.


Subject(s)
Phosphorus/chemistry , Rivers/chemistry , Water Movements , Water Pollution, Chemical/prevention & control , Water Quality , Agriculture/methods , Climate Change , Conservation of Natural Resources , England , Models, Theoretical , Sensitivity and Specificity
11.
Sci Total Environ ; 424: 193-201, 2012 May 01.
Article in English | MEDLINE | ID: mdl-22425276

ABSTRACT

To understand the resilience of aquatic ecosystems to environmental change, it is important to determine how multiple, related environmental factors, such as near-surface air temperature and river flow, will change during the next century. This study develops a novel methodology that combines statistical downscaling and fish species distribution modeling, to enhance the understanding of how global climate changes (modeled by global climate models at coarse-resolution) may affect local riverine fish diversity. The novelty of this work is the downscaling framework developed to provide suitable future projections of fish habitat descriptors, focusing particularly on the hydrology which has been rarely considered in previous studies. The proposed modeling framework was developed and tested in a major European system, the Adour-Garonne river basin (SW France, 116,000 km(2)), which covers distinct hydrological and thermal regions from the Pyrenees to the Atlantic coast. The simulations suggest that, by 2100, the mean annual stream flow is projected to decrease by approximately 15% and temperature to increase by approximately 1.2 °C, on average. As consequence, the majority of cool- and warm-water fish species is projected to expand their geographical range within the basin while the few cold-water species will experience a reduction in their distribution. The limitations and potential benefits of the proposed modeling approach are discussed.


Subject(s)
Climate Change , Conservation of Natural Resources/methods , Ecosystem , Fishes/physiology , Fresh Water , Models, Biological , Animals , Biota , Climate , France , Water Movements
12.
Sci Total Environ ; 412-413: 315-23, 2011 Dec 15.
Article in English | MEDLINE | ID: mdl-22055657

ABSTRACT

High rates of nutrient loading from agricultural and urban development have resulted in surface water eutrophication and groundwater contamination in regions of Ontario. In Lake Simcoe (Ontario, Canada), anthropogenic nutrient contributions have contributed to increased algal growth, low hypolimnetic oxygen concentrations, and impaired fish reproduction. An ambitious programme has been initiated to reduce phosphorus loads to the lake, aiming to achieve at least a 40% reduction in phosphorus loads by 2045. Achievement of this target necessitates effective remediation strategies, which will rely upon an improved understanding of controls on nutrient export from tributaries of Lake Simcoe as well as improved understanding of the importance of phosphorus cycling within the lake. In this paper, we describe a new model structure for the integrated dynamic and process-based model INCA-P, which allows fully-distributed applications, suited to branched river networks. We demonstrate application of this model to the Black River, a tributary of Lake Simcoe, and use INCA-P to simulate the fluxes of P entering the lake system, apportion phosphorus among different sources in the catchment, and explore future scenarios of land-use change and nutrient management to identify high priority sites for implementation of watershed best management practises.


Subject(s)
Environmental Monitoring/methods , Models, Chemical , Phosphorus/chemistry , Rivers/chemistry , Water Pollutants, Chemical/chemistry , Conservation of Natural Resources , Ecosystem , Eutrophication , Lakes/chemistry , Ontario , Seasons , Water Movements
13.
Philos Trans A Math Phys Eng Sci ; 368(1931): 5151-72, 2010 Nov 28.
Article in English | MEDLINE | ID: mdl-20956366

ABSTRACT

This paper is concerned with the quantification of the likely effect of anthropogenic climate change on the water resources of Jordan by the end of the twenty-first century. Specifically, a suite of hydrological models are used in conjunction with modelled outcomes from a regional climate model, HadRM3, and a weather generator to determine how future flows in the upper River Jordan and in the Wadi Faynan may change. The results indicate that groundwater will play an important role in the water security of the country as irrigation demands increase. Given future projections of reduced winter rainfall and increased near-surface air temperatures, the already low groundwater recharge will decrease further. Interestingly, the modelled discharge at the Wadi Faynan indicates that extreme flood flows will increase in magnitude, despite a decrease in the mean annual rainfall. Simulations projected no increase in flood magnitude in the upper River Jordan. Discussion focuses on the utility of the modelling framework, the problems of making quantitative forecasts and the implications of reduced water availability in Jordan.


Subject(s)
Climate Change , Water Supply , Conservation of Natural Resources , Forecasting , Jordan , Models, Theoretical , Rivers , Seasons , Water Cycle/physiology , Water Movements , Weather
14.
Sci Total Environ ; 400(1-3): 52-74, 2008 Aug 01.
Article in English | MEDLINE | ID: mdl-18538825

ABSTRACT

The Integrated Catchment Model of Nitrogen (INCA-N) was applied to the River Lambourn, a Chalk river-system in southern England. The model's abilities to simulate the long-term trend and seasonal patterns in observed stream water nitrate concentrations from 1920 to 2003 were tested. This is the first time a semi-distributed, daily time-step model has been applied to simulate such a long time period and then used to calculate detailed catchment nutrient budgets which span the conversion of pasture to arable during the late 1930s and 1940s. Thus, this work goes beyond source apportionment and looks to demonstrate how such simulations can be used to assess the state of the catchment and develop an understanding of system behaviour. The mass-balance results from 1921, 1922, 1991, 2001 and 2002 are presented and those for 1991 are compared to other modelled and literature values of loads associated with nitrogen soil processes and export. The variations highlighted the problem of comparing modelled fluxes with point measurements but proved useful for identifying the most poorly understood inputs and processes thereby providing an assessment of input data and model structural uncertainty. The modelled terrestrial and instream mass-balances also highlight the importance of the hydrological conditions in pollutant transport. Between 1922 and 2002, increased inputs of nitrogen from fertiliser, livestock and deposition have altered the nitrogen balance with a shift from possible reduction in soil fertility but little environmental impact in 1922, to a situation of nitrogen accumulation in the soil, groundwater and instream biota in 2002. In 1922 and 2002 it was estimated that approximately 2 and 18 kg N ha(-1) yr(-1) respectively were exported from the land to the stream. The utility of the approach and further considerations for the best use of models are discussed.


Subject(s)
Nitrogen/analysis , Water Pollutants, Chemical/analysis , England , Geography , Models, Chemical , Nitrates/analysis , Plants/metabolism , Quaternary Ammonium Compounds/analysis , Rivers/chemistry , Seasons , Water Movements
15.
Sci Total Environ ; 365(1-3): 260-73, 2006 Jul 15.
Article in English | MEDLINE | ID: mdl-16603230

ABSTRACT

The impacts of climate change on nitrogen (N) in a lowland chalk stream are investigated using a dynamic modelling approach. The INCA-N model is used to simulate transient daily hydrology and water quality in the River Kennet using temperature and precipitation scenarios downscaled from the General Circulation Model (GCM) output for the period 1961-2100. The three GCMs (CGCM2, CSIRO and HadCM3) yield very different river flow regimes with the latter projecting significant periods of drought in the second half of the 21st century. Stream-water N concentrations increase over time as higher temperatures enhance N release from the soil, and lower river flows reduce the dilution capacity of the river. Particular problems are shown to occur following severe droughts when N mineralization is high and the subsequent breaking of the drought releases high nitrate loads into the river system. Possible strategies for reducing climate-driven N loads are explored using INCA-N. The measures include land use change or fertiliser reduction, reduction in atmospheric nitrate and ammonium deposition, and the introduction of water meadows or connected wetlands adjacent to the river. The most effective strategy is to change land use or reduce fertiliser use, followed by water meadow creation, and atmospheric pollution controls. Finally, a combined approach involving all three strategies is investigated and shown to reduce in-stream nitrate concentrations to those pre-1950s even under climate change.


Subject(s)
Calcium Carbonate/analysis , Climate , Nitrogen/analysis , Rivers/chemistry , Water Pollutants/analysis , Agriculture , Air Pollution/analysis , Ammonia/analysis , Ammonia/metabolism , Fertilizers , Geologic Sediments/chemistry , Minerals/chemistry , Models, Biological , Nitrates/analysis , Nitrates/metabolism , Nitrogen/metabolism , Seasons , Soil Pollutants/analysis , Temperature , Time Factors , Water Movements
16.
Sci Total Environ ; 294(1-3): 73-94, 2002 Jul 22.
Article in English | MEDLINE | ID: mdl-12169013

ABSTRACT

Land above 300 m covers approximately 75% of the surface of Scotland and most of the nation's major river systems have their headwaters in this upland environment. The hydrological characteristics of the uplands exert an important influence on the hydrochemistry of both headwater streams and downstream river systems. Thus, many of the spatial and temporal patterns in the chemical quality of surface waters are mediated by hydrological processes that route precipitation through upland catchments. These hydrological pathways also have an important influence on how the hydrochemistry of upland streams is responding to increasing pressures from environmental changes at the global and regional scales. At the present time, atmospheric deposition remains an issue in many parts of the Scottish uplands, where critical loads of acidity are exceeded, particularly in areas affected by increasing N deposition. Moreover, climatic change forecasts predict increasingly wetter, warmer and more seasonal conditions, which may modify the hydrochemical regimes of many river systems, particularly those with a strong snowmelt component. On a more localised scale, land management practices, including felling of commercial forests, expansion of native woodlands, agricultural decline and moorland management all have implications for the freshwater environment. Moreover, increasing public access to upland areas for a range of recreational activities have implications for water quality. Understanding the hydrology of the uplands, through integrated field and modelling studies, particularly of the hydrological pathways that regulate chemical transfers to streamwaters, will remain an important research frontier for the foreseeable future.


Subject(s)
Conservation of Natural Resources , Models, Theoretical , Recreation , Water Pollutants/analysis , Water/chemistry , Climate , Environmental Monitoring , Hydrogen-Ion Concentration , Scotland , Seasons
17.
Sci Total Environ ; 282-283: 143-57, 2002 Jan 23.
Article in English | MEDLINE | ID: mdl-11846068

ABSTRACT

An initial study to observe the seasonal trends and to determine the factors influencing macrophyte and periphyton growth patterns was undertaken on a representative reach of the River Kennet (UK) over a 2-year period (1998-2000). Maximum average macrophyte and average periphyton dry matter biomass recorded during the growing season were 200 and 21 g m(-2), respectively. The relationships between macrophyte and periphyton percentage cover and biomass data with physico-chemical variables were investigated. Regression analysis indicated that of the parameters measured, flow, and in the case of the dominant Ranunculus spp., solar radiation, were best able to predict macrophyte biomass and cover. The periphytic biomass within the reach was low, possibly as a result of relatively high flows and low phosphorus concentrations following the introduction of effluent treatment at the sewage works immediately upstream of the reach. Periphytic biomass was poorly correlated with the physical variables measured. This indicates that biomass is regulated by complex interactions between the physical and chemical factors, such as flow, solar radiation and phosphorus concentration. These interrelationships require further investigation.


Subject(s)
Eukaryota , Plants , Water Pollutants/adverse effects , Biomass , Calcium Carbonate , Phosphorus , Population Dynamics , Seasons , Sewage , Sunlight , Water Movements
18.
Sci Total Environ ; 282-283: 327-40, 2002 Jan 23.
Article in English | MEDLINE | ID: mdl-11846077

ABSTRACT

The spatial and temporal variations in calcite (calcium carbonate) solubility within the Dee basin of NE Scotland were assessed using water chemistry data gathered from a network of 59 sites monitored for water quality from June 1996 to May 1997. Calcite solubility, expressed in terms of a saturation index (SIcalcite), was determined from measured streamwater pH, Gran alkalinity and calcium concentrations and water temperature. In general, the waters of the Dee system are undersaturated with respect to calcite, though the saturation index is higher during the summer months indicating a dependency on flow conditions and biological activity. Under low-flow conditions, the streamwaters are dominated by water derived from the lower soil horizons and deeper groundwater stores and therefore, ions such as Gran alkalinity and calcium are at their highest concentrations as they are derived mainly from bedrock weathering. The influence of biological activity on the carbonate system is also evident as the observed pH and estimated EpCO2 values indicate strong seasonal patterns, with the highest pH and lowest EpCO2 values occurring during the summer low-flow periods. Only at three sites in the lowland region of the catchment, during the summer low-flow period, are the waters oversaturated. As such, the Dee system represents an extreme 'end-member' case when compared to many UK rivers that span both under- and oversaturated conditions during the year. Regression analysis highlights a systematic change in the SIcalcite-pH relationship in a broad east-west direction across the Dee system. At sites draining the relatively impermeable upland areas, the regression of SIcalcite against pH gives a straight line with a gradient in the range 1.6-2.4. Correspondingly, under the most extreme alkaline conditions found at sites draining lowland agricultural areas, a straight-line relationship exists but with a gradient of unity. It is concluded that these changes in the SIcalcite-pH relationship are due to variations in the bicarbonate system induced by the flow conditions and biological activity. Given the waters are undersaturated, then calcite precipitation and hence phosphorus co-precipitation cannot occur within the water column.


Subject(s)
Calcium Carbonate/analysis , Water Microbiology , Agriculture , Calcium Carbonate/chemistry , Geological Phenomena , Geology , Hydrogen-Ion Concentration , Oxygen/metabolism , Phosphorus/analysis , Scotland , Seasons , Solubility , Temperature , Water/chemistry , Water Movements
19.
Sci Total Environ ; 282-283: 375-93, 2002 Jan 23.
Article in English | MEDLINE | ID: mdl-11846080

ABSTRACT

A new in-stream model of phosphorus (P) and macrophyte dynamics, the Kennet Model, was applied to a reach of the River Kennet to investigate the impacts of changing flow conditions on macrophyte growth. The investigation was based on the assessment of two flow change scenarios, which both included the simulation of decreasing total phosphorus concentrations from a sewage treatment works due to improved effluent treatment. In the first scenario, the precipitation and potential evaporation outputs from a climate change model (HadCM2 GGx) where input into the catchment model INCA to predict the mean daily flows in the reach. In the second scenario, the mean daily flows observed in a historically dry year were repeated as input to the in-stream model to simulate an extended low flow period over 2 years. The simulation results suggest that changes in the seasonal distribution of flow were not detrimental to macrophyte growth. However, the simulation of extended periods of low flow suggests that a proliferation of epiphytic algae occurs, even when the in-stream phosphorus concentrations are reduced due to effluent treatment. This epiphytic growth was predicted to reduce the macrophyte peak biomass within the reach by approximately 80%. Thus, the model simulations suggest that flow was more important in controlling the macrophyte biomass in the River Kennet, than the in-stream phosphorus concentrations, which are elevated due to agricultural diffuse sources.


Subject(s)
Eukaryota , Eutrophication , Models, Theoretical , Phosphorus/analysis , Plants , Water Movements , Agriculture , Biomass , Chemical Precipitation , England , Population Dynamics , Seasons , Volatilization , Water/chemistry
20.
Sci Total Environ ; 282-283: 395-415, 2002 Jan 23.
Article in English | MEDLINE | ID: mdl-11846081

ABSTRACT

A new model of in-stream phosphorus and macrophyte dynamics, 'The Kennet model', was applied to a reach of the River Kennet, southern England. The reach, which is 1.5 km long, is immediately downstream of Marlborough sewage treatment works, where phosphorus reduction by tertiary effluent treatment began in September 1997. The model is used to simulate the flow, water chemistry and macrophyte biomass within the reach, both before and after phosphorus removal from the effluent. Monte Carlo experiments coupled with a general sensitivity analysis indicate that the model offers a feasible explanation for the salient aspects of the system behaviour. Model simulations indicate that epiphyte smothering is an important limitation to macrophyte growth, and that higher stream and pore water soluble reactive phosphorus (SRP) concentrations allow the earlier onset of growth for the epiphytes and macrophytes, respectively. Higher flow conditions are shown to reduce the simulated peak epiphyte biomass; though at present, the effect of flow on the macrophyte biomass is unclear. Another simulation result suggests that phosphorus will not be released from the bed sediments in this reach following phosphorus removal from the effluent.


Subject(s)
Eukaryota , Eutrophication , Models, Theoretical , Phosphorus/chemistry , Plants , Sewage/chemistry , Biomass , Geologic Sediments , Phosphorus/analysis , Population Dynamics , Solubility , Water/chemistry
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