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2.
Nat Commun ; 8: 15944, 2017 06 20.
Article in English | MEDLINE | ID: mdl-28631724

ABSTRACT

In light of directives around the world to eliminate toxic materials in various technologies, finding lead-free materials with high piezoelectric responses constitutes an important current scientific goal. As such, the recent discovery of a large electromechanical conversion near room temperature in (1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 compounds has directed attention to understanding its origin. Here, we report the development of a large-scale atomistic scheme providing a microscopic insight into this technologically promising material. We find that its high piezoelectricity originates from the existence of large fluctuations of polarization in the orthorhombic state arising from the combination of a flat free-energy landscape, a fragmented local structure, and the narrow temperature window around room temperature at which this orthorhombic phase is the equilibrium state. In addition to deepening the current knowledge on piezoelectricity, these findings have the potential to guide the design of other lead-free materials with large electromechanical responses.

3.
J Phys Condens Matter ; 29(25): 254001, 2017 Jun 28.
Article in English | MEDLINE | ID: mdl-28516894

ABSTRACT

A toy model combining the angular magneto electric (AME) coupling Hamitonian (Mondal et al 2015 Phys. Rev. B 92 100402) with long-range magnetic dipolar interactions is used to investigate spin-torque phenomena in a magnetic spin valve. It is found that such model (1) gives rise to spin-torque expressions that are analogous in form to those of the common spin-transfer torques; but also (2) predicts additional spin-torque terms, which are generated by an electrical current oriented along unconventional, in-plane directions. The magnitude of the AME induced terms is estimated and the conditions under which they may contribute significantly are explored.

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