Materials in Radiative Cooling Technologies.

Radiative cooling (RC) is a carbon-neutral cooling technology that utilizes thermal radiation to dissipate heat from the Earth's surface to the cold outer space. Research in the field of RC has garnered increasing interest from both academia and industry due to its potential to drive sustainable economic and environmental benefits to human society by reducing energy consumption and greenhouse gas emissions from conventional cooling systems. Materials innovation is the key to fully exploit the potential of RC. This review aims to elucidate the materials development with a focus on the design strategy including their intrinsic properties, structural formations, and performance improvement. The main types of RC materials, i.e., static-homogeneous, static-composite, dynamic, and multifunctional materials, are systematically overviewed. Future trends, possible challenges, and potential solutions are presented with perspectives in the concluding part, aiming to provide a roadmap for the future development of advanced RC materials.

High sensitivity graphene based health sensor with self-warning function.

In order to reduce the damage to people's health from diseases that attack the respiratory system such as COVID-19, asthma, and pneumonia, it is desired that patients' breathing can be monitored and alerted in real-time. The emergence of wearable health detection sensing devices has provided a relatively good response to this problem. However, there are still problems such as complex structure and poor performance. This paper introduces a laser-induced graphene (LIG) device that is attached to PDMS. The LIG is produced by laser irradiation of Nomex and subsequently transferred and attached to the PDMS. After being tested, it has demonstrated high sensitivity, stable tensile performance, good acoustic performance, excellent thermal stability, and other favorable properties. Notably, its gauge factor (GF) value can reach 721.67, which is quite impressive. Additionally, it is capable of emitting an alarm sound with an SPL close to 60 dB when receiving signals within the range of 5-20 kHz. The device realizes mechanical sensing and acoustic functions in one chip, and has a high application value in applications that need to combine sensing and early warning.

Theoretical analysis of the absorption of CO2 and CO on pristine and Al-doped C3B.

CO2 and CO, the by-products of fossil fuels; one of them is a major cause of global warming and the other endangers the nervous and cardiovascular systems of humans. Therefore, real-time monitoring towards those harmful gases is of practical significance. Nano-structured materials have attracted the attention of scholars for their enormous potential for harmful gas detection. In this work, the adsorption and sensing behavior of C3B and Al-doped C3B monolayers for these two typical hazardous gases were investigated theoretically. The most stable doping model was obtained, and the adsorption process for CO and CO2 was simulated based on this model. The adsorption system shows that the gas molecules are all deformed and that the charge transfer and adsorption energy are significantly increased. Moreover, the adsorption mechanism was investigated by analyzing the electronic behavior of the adsorbent, and the physical adsorption between the hazardous gas and the adsorbent was more favorable for desorption. The good adsorption performance and sensing mechanism suggest that the CO/CO2 sensor prepared using Al-C3B has great potential for application. Our work may provide some guidance for the application of toxic gas monitoring and adsorption.

Humidity-Based Human-Machine Interaction System for Healthcare Applications.

Human-machine interaction (HMI) systems are widely used in the healthcare field, and they play an essential role in assisting the rehabilitation of patients. Currently, a large number of HMI-related research studies focus on piezoresistive sensors, self-power sensors, visual and auditory receivers, and so forth. These sensing modalities do not possess high reliability with regard to breathing condition detection. The humidity signal conveyed by breathing provides excellent stability and a fast response; however, humidity-based HMI systems have rarely been studied. Herein, we integrate a humidity sensor and a graphene thermoacoustic device into a humidity-based HMI system (HHMIS), which is capable of monitoring respiratory signals and emitting acoustic signals. HHMIS has a practical value in healthcare to assist patients. For example, it works as a prewarning system for respiratory-related disease patients with abnormal respiratory rates, and as an artificial throat device for aphasia patients. Achieved based on a laser direct writing technology, this wearable device features low cost, high flexibility, and can be prepared on a large scale. This portable non-contact HMMIS has broad application prospects in many fields such as medical health and intelligent control.

An investigation of the positive effects of doping an Al atom on the adsorption of CO2 on BN nanosheets: a DFT study.

Nowadays, climate problems caused by greenhouse gases are becoming more and more serious. Motivated by reducing carbon dioxide emissions from fossil fuel power generation, scientists are devoting themselves to developing novel materials or technologies for capturing carbon dioxide. Nanostructure materials, which show great potential for this application, have come to the attention of scientists. Herein, the effects of doping an aluminum atom (replacing one boron atom by one aluminum one) on the adsorption of carbon dioxide on boron nitride nanosheets are theoretically investigated through computational analysis based on density functional theory. The results show that the binding between oxygen and aluminum atoms, which comes from classical Lewis base (CO2)-Lewis acid (Al) interactions, can provide a considerable gain to the mutual effect between the carbon dioxide molecule and the doped substrate. Compared with pristine boron nitride nanosheets, the adsorption energy value of the carbon dioxide molecule is markedly increased to 0.4784 eV (about 2.5-fold) after the doping process, which is in the range of the ideal adsorption energy of 0.415-0.829 eV. More importantly, the essence of physisorption signifies that carbon dioxide can be released by means of specific physical desorption, and, sequentially, this is more conducive for achieving reversible adsorption.

A Crop Classification Method Integrating GF-3 PolSAR and Sentinel-2A Optical Data in the Dongting Lake Basin.

With the increasing of satellite sensors, more available multi-source data can be used for large-scale high-precision crop classification. Both polarimetric synthetic aperture radar (PolSAR) and multi-spectral optical data have been widely used for classification. However, it is difficult to combine the covariance matrix of PolSAR data with the spectral bands of optical data. Using Hoekman's method, this study solves the above problems by transforming the covariance matrix to an intensity vector that includes multiple intensity values on different polarization basis. In order to reduce the features redundancy, the principal component analysis (PCA) algorithm is adopted to select some useful polarimetric and optical features. In this study, the PolSAR data acquired by satellite Gaofen-3 (GF-3) on 19 July 2017 and the optical data acquired by Sentinel-2A on 17 July 2017 over the Dongting lake basin are selected for the validation experiment. The results show that the full feature integration method proposed in this study achieves an overall classification accuracy of 85.27%, higher than that of the single dataset method or some other feature integration modes.

Two-dimensional gratings of hexagonal holes for high order diffraction suppression.

We propose two-dimensional gratings comprised of a large number of identical and similarly oriented hexagonal holes for the high order diffraction suppression. An analytical study of the diffraction property for such gratings, based on both square and triangle arrays, is described. The dependence of the high order diffraction property on the hole shape and size is investigated. Notably, theoretical calculation reveals that the 2nd, 3rd and 4th order diffractions adjacent to the 1st order diffraction can be completely suppressed, and the 5th order diffraction efficiency is as low as 0.01%, which will be submerged in the background noise for most practical applications. The 1st order diffraction intensity efficiency 6.93% can be achieved as the hexagonal holes along y-axis connect with each other. For the case of b=Py/3, the 1st order diffraction intensity efficiency is 3.08%. The experimental results are also presented, confirming the theoretical predictions. Especially, our two-dimensional gratings have the ability to form free-standing structures which are highly desired for the x-ray region. Comparing with the grating of the square array, the grating of the triangle array is easy to be fabricated by silicon planar process due to the large spacing between any two adjacent holes. Our results should be of great interest in a wide spectrum unscrambling from the infrared to the x-ray region.