Spatiotemporal dynamics and influencing factors of CO2 emissions under regional collaboration: Evidence from the Beijing-Tianjin-Hebei region in China.

Against the backdrop of global climate change and the "dual carbon" target, cities have a significant responsibility to achieve carbon reduction targets. As a crucial urban agglomeration in northern China, effectively balancing economic growth with CO2 emission reduction to achieve high-quality economic development remains a significant challenge that the Beijing-Tianjin-Hebei region should address both presently and in the future. The objective of this study is to utilize nighttime lighting data and energy consumption information to quantify the CO2 emissions of diverse cities within the Beijing-Tianjin-Hebei region spanning from 2006 to 2020. The research aims to analyze the spatial progression patterns of CO2 emissions across these urban centers, identify key determinants and their interrelations, and delve into the underlying mechanisms pivotal for advancing carbon mitigation strategies within urban agglomerations. The results indicate that: with an exception in Beijing where CO2 emissions slightly decreased compared to 2006, CO2 emissions increased across cities in the Beijing-Tianjin-Hebei region by 2020. High-value CO2 emission areas are primarily concentrated in central of the study area, exhibiting negative spatial correlation characteristics. Based on its urban development positioning, it is imperative for the Beijing-Tianjin-Hebei urban agglomeration to formulate and implement carbon reduction strategies on innovative development, industrial upgrading, and ecological protection among other aspects towards coordinated low-carbon development.

Spatial distribution characteristics of natural ecological resilience in China.

High-intensity exploitation of land resources and the natural environment can upset the balance of ecosystems, causing multiple ecological problems and affecting regional sustainable development. Recently, China has carried out integrated regional ecosystem protection and restoration governance. Ecological resilience (ER) is the foundation of and key to achieving sustainable regional development. Based on the significance of ER in ecological protection and restoration efforts and the necessity of conducting large-scale studies, we conducted relevant research on the ER in China. In this study, we selected typical impact factors to construct an assessment model of ER in China and quantitatively measured its large-scale spatial and temporal distribution characteristics, while also exploring the relationship between ER and land-use types. The country was zoned according to the ER contributions of each land-use type, and ER enhancement and ecological protection were discussed based on the characteristics of different regions. The ER in China shows clear spatial heterogeneity and spatial agglomeration, roughly represented by high and low ER in the southeast and northwest regions. The mean ER values of woodland, arable land, and construction land were all greater than 0.6, with more than 97% of the ER values at levels of medium or above. The country can be divided into three regions based on the degree of ER contributions of various land-use types, each with different ecological problems. This study provides a detailed understanding of and explores the important role of ER on the regional development process, and provides support and reference for regional ecological protection and restoration as well as sustainable development.

Source apportionment and potential ecological risk assessment of heavy metals in soils on a large scale in China.

The properties and sources of soil heavy metals (Pb, Zn, Cu, Cd, As, Hg, Cr, and Ni) need to be comprehensively analyzed to take effective steps to control and reduce soil pollutants. In this research, 416 soil samples were collected on a large scale in China. Two receptor models (PCA/MLR and PMF) were utilized to identify pollutant sources and quantify the contributions. The means of soil heavy metals (Zn, Cu, As, Hg, Cr, and Ni) were lower than the corresponding screening values and intervention values. Cd was greater than the intervention value, while Pb was between the screening value and the intervention value. Source apportionments suggested that mine sources were the most polluted (64.28%), followed by traffic sources (38.98%), natural sources (11.41-39.58%), industrial sources (9.8-18.65%), and agricultural sources (2.79-14.51%). Compared to the PCA/MLR model, the PMF model had a better effect in evaluating soil heavy metal pollution. It gave corresponding weights according to the data concentration and its uncertainty, which made the result reasonable. The ecological risk assessment indicated that Cd posed a significant risk, while Hg caused a mild risk and the other six heavy metals posed a low risk. The spatial distribution of ecological risk suggested that severe risk points were mainly distributed in the central area, while high-risk points were distributed in the southern region. The SRI method was developed to link pollution sources and their potential ecological risks and indicated better applicability to the PMF model. The study findings could provide guidelines for monitoring the main sources and reducing the pollution of soil heavy metals.

The payment scheme for ecosystem services in the coastal city based on the ecosystem services value and current payment efficiency: a case study in Jimo of Qingdao city, China.

The reasonable strategies of payment for ecosystem services (PES) play a key role in solving the contradiction between ecological protection and economic development in coastal cities. However, at present, the payment efficiency is relatively low and the determination method of PES is lack. Therefore, in this study, the Jimo district of Qingdao city in China, a typical coastal city, was selected as study area, and the equivalent factor method and marine ecological capital assessment method were used to obtain terrestrial and marine ecosystem services value (ESV) and its tempo-spatial variations from 2010 to 2018. Moreover, the payment efficiency of the sea area and 15 towns over 8 years was measured using the Super-efficient SBM-DEA model based on undesired output. ESV presented a clear reduction over 8 years. The marine ecosystem provided the main service value, and waste treatment, water regulation, and soil formation were the top 3 main functions in the land ecosystem. Regulating services provided the highest component among all functions. The high-value areas were mainly distributed in the northeast and northwest regions and the low-value areas were in the south-central regions. The average payment efficiency of the sea area and 15 towns over 8 years shown a stable trend at a low level. On the basis of the evaluation of ESV and efficiency, a new possible payment scheme including payment order and quota was proposed. The total quota of marine ecosystem was 5.226 billion RMB (88% of the total) and of terrestrial ecosystem was 0.713 billion RMB. Tian Heng, Jin Kou, Yi Fengdian, and Ling Shan are the first 4 priority towns, with compensation amounts of 0.205, 0.083, and 0.063 billion RMB respectively, while the last 3 towns are Tong Ji, Huan Xiu, and Chao Hai accounting for 6.02% of the total. The theoretical payment total quota was 5.939 billion RMB, and which accounted for a low proportion of local GDP. The study can provide some recommendations for making the reasonable and feasible payment schemes for ecosystem services in coastal city, and it is feasible in the practice of ecological environment protection and sustainable development.

Spatiotemporal dynamic differences of energy-related CO2 emissions and the related driven factors in six regions of China during two decades.

Carbon neutrality lays out a grand blueprint for carbon emission reduction and climate governance in China. How to reduce energy consumption is the key to achieving this goal. The economic development and energy consumption show a very large gap at the provincial level, and this paper divides China into six regions (North, Northeast, East, Mid-South, Southwest, and Northwest) and analyzes the dynamic changes and reveals the driving factors that have affected CO2 emission changes from 1997 to 2017. Then, the driving forces including energy intensity, energy structure, energy efficiency, economic activity, and population scale were discussed employing the logarithmic mean Divisia index (LMDI) based on provincial panel data. The results show that CO2 emissions from energy consumption show an upward trend, from 4145 Mt in 1997 to 13,250 Mt in 2017, with an annual average growth rate of 1.06%; coal consumption is the main source of CO2 emission. The regions with the highest proportion of CO2 emissions are the East and North, which account for 50% of total emissions. China's CO2 emissions from energy consumption, coal consumption, and output have shown significant spatial autocorrelation at the provincial scale. According to coal consumption, energy consumption CO2 emissions are divided into three stages: phase I (1997-2002), the increase in CO2 emissions in six regions was attributed to significant and positive impacts of energy intensity, economic activity, and population scale, the effects of which exceeded those of the energy structure and energy efficiency; phase II (2003-2012), the economic activity effect on CO2 emissions was highest in the East region, followed by the North and Mid-South regions; phase III (2013-2017), the East, Mid-South, and Southwest regions of China were dominated by the positive effects of energy intensity, economic activity, and population scale. The major driver of CO2 emissions is economic activity; the energy efficiency effect is an important inhibitory factor. Regional economic development and energy consumption in China are unbalanced; we conclude that differentiated emission reduction measures should be of particular concern for policymakers.

Polystyrene nanoplastics cause growth inhibition, morphological damage and physiological disturbance in the marine microalga Platymonas helgolandica.

Effects of nanoplastics at low level on the marine primary producer are largely unclear. To assess the potential risk of nanoplastic pollution, this study exposed marine green microalgae Platymonas helgolandica to 20, 200, and 2000 µg/L 70-nm polystyrene nanoplastics for 6 days. Nanoplastics significantly inhibited the growth of P. helgolandica during the first 4 days of exposure, and elevated heterocyst frequency was observed in 200 and 2000 µg/L exposure groups in the early exposure stage. Exposure to 200 and 2000 µg/L nanoplastics for 4 days increased the membrane permeability and mitochondrial membrane potential, and decreased light energy used in photochemical processes of microalgae. Moreover, clear morphological changes, including surface folds, fragmentation, aggregation cluster, and rupture, in the microalgae exposed to nanoplastics were observed under scanning electron microscope and transmission electron microscope. These results demonstrate that nanoplastics could reduce the microalgal vitality by the damage on cell morphology and organelle function.

Spatiotemporal variation and influencing factors of vegetation cover in the ecologically fragile areas of China from 2000 to 2015: a case study in Shaanxi Province.

China's Loess Plateau region has a weak ecological environment, and the government has invested a considerable amount of money to repair the ecological environment. Vegetation plays an important role in the ecological environment. The Sen slope analysis and the Mann-Kendall trend test were used to analyze the trend and significance of vegetation coverage from 2000 to 2015. The vegetation coverage was analyzed to investigate the influence of land use types and conversion. The Pearson Correlation Test and qualitative analysis were utilized at the pixel and regional scales to investigate the influence of meteorological factors and topographical factors. The fluctuation of vegetation in Shaanxi was analyzed from 2000 to 2015. The impact of anthropogenic activities was investigated using residual trend analysis. Hurst exponent and H/S analysis were applied to investigate the potential future vegetation coverage trend. The vegetation coverage in Shaanxi Province improved from 2000 to 2015. In unchanged land use types, all types showed significant improvements expect for other construction land. In changed land use types, most of the land use types converted into urban land showed degradation. All the land use types converted into dry land, forest, and unused land showed improvements. Ecological protection has achieved great results. Precipitation and temperature partly affect vegetation coverage in Shaanxi. Gradients and elevation affected the distribution of vegetation coverage and human activities influenced land use type and the ecological environment. In the future, potential degradation risks still exist in the parts of Shaanxi Province.

Linking the reclaimed soils and rehabilitated vegetation in an opencast coal mining area: a complex network approach.

As two main factors, soil and vegetation play key roles in land rehabilitation and ecological remediation of mining areas. There is a complex interaction between soil and vegetation, and understanding the mechanisms of interaction between soil and vegetation is of great significance for land rehabilitation and ecological remediation in mining areas. This study introduced complex network method to analyze the complex interaction systematically. A survey of vegetation and soil properties in 70 reclaimed plots was carried out in the Anjialing and Antaibao opencast coal-mines in Shanxi, China. The indices of soil and vegetation acted as nodes, and the interaction between these indices as sides to establish a soil-vegetation network. Calculating the network indices to analyze the structure of a complex network and explore the mechanism of interaction between soil and vegetation. SOM (soil organic matter) was at the core of the soil-vegetation interaction network. The average path length of the soil-vegetation network was 1.8, with a faster rate of information transfer. The soil-vegetation network consisted of three clusters (soil physical property cluster, soil chemical property cluster, and vegetation cluster), in which the soil chemical property cluster owned the highest clustering coefficient and the largest number of triangles, and it was most stable and the interaction within the cluster was strongest. The soil-vegetation network was stable and the connectivity of the network had robustness to node failures. The scale of the network became larger and the network became tighter and more stable with the increase of reclamation time. Some measures should be conducted to promote vegetation restoration by improving important soil nodes, e.g., surface soil covering, applying organic fertilizer, and planting nitrogen-fixing plants.

Fabrication and characterization of a novel corn straw/modified ammonium lignosulfonate bio-composite strengthened by polyethylenimine pretreatment.

This study focuses on the development of novel bio-composites via the pretreatment of corn straw particles (PCSP) and modified ammonium lignosulfonate (MAL) as a binder. The corn stalk particles (CSP) were pretreated with polyethylenimine (PEI) to enhance compatibility. The effects of PEI dosage on the mechanical properties and dimensional stability were examined, where PEI pretreatment improved the interfacial properties of MAL and CSP considerably. The optimum values of the PCSP/MAL composites complied with the Chinese national standard for load-bearing particleboard. Furthermore, the results confirmed that PEI pretreatment resulted in good surface activity and exhibited a favorable effect on the crystallinity of the PCSP/MAL composites. The storage moduli E' and tan δ peak of the PCSP/MAL composites were considerably greater than those of the CSP/MAL composites. The fractured morphology of the composites clearly showed that PEI pretreatment improves the interfacial adhesion of MAL and CSP.

Life cycle assessment of opencast coal mine production: a case study in Yimin mining area in China.

China has the largest coal production in the world due to abundant resource requirements for economic development. In recent years, the proportion of opencast coal mine production has increased significantly in China. Opencast coal mining can lead to a large number of environmental problems, including air pollution, water pollution, and solid waste occupation. The previous studies on the environmental impacts of opencast coal mine production were focused on a single production process. Moreover, mined land reclamation was an important process in opencast coal mine production; however, it was rarely considered in previous research. Therefore, this study attempted to perform a whole environmental impact analysis including land reclamation stage using life cycle assessment (LCA) method. The Yimin opencast coal mine was selected to conduct a case study. The production of 100 tons of coal was used as the functional unit to evaluate the environmental risks in the stages of stripping, mining, transportation, processing, and reclamation. A total of six environmental impact categories, i.e., resource consumption, acidification, global warming, solid waste, eutrophication, and dust, were selected to conduct this assessment. The contribution rates of different categories of environmental impacts were significantly different, and different stages exhibited different consumption and emissions that gave rise to different environmental effects. Dust was the most serious environmental impact category, and its contribution rate was 36.81%, followed by global warming and acidification with contribution rates of 29.43% and 22.58%, respectively. Both dust and global warming were mainly affected in mining stage in Yimin opencast coal mine based on comprehensive analysis of environmental impact. Some economic and feasible measures should be used to mitigate the environmental impacts of opencast coal mine production, such as water spraying, clean transportation, increasing processing efficiency, and improving mining technologies. This study can be considered as a useful reference for a deeper understanding of key environmental impacts related to the whole coal production in opencast coal mine.

Influence of soil physical properties and vegetation coverage at different slope aspects in a reclaimed dump.

Vegetation coverage is an important parameter for affecting soil erosion and the physical and chemical properties of soil. To analyze the mutual influence between vegetation coverage and soil quality at different slope aspects in a reclaimed dump, fitting analyses were built between the normalized difference vegetation index and soil physical properties at each slope aspect. Twenty six quadrats were sampled in slope-platform alternate mode. Each quadrat was 10 m × 10 m. Vegetation index and soil physical properties were measured and calculated. Through curve fitting analysis, the results showed that soil bulk density has a negative correlation with the vegetation index on shady and half shady slopes, sunny slopes, and half sunny slopes. Soil porosity has a positive correlation with the vegetation index on shady and half shady slopes, sunny slope, and half sunny slope. The soil mass water content has a concave function relationship with the vegetation index on shady and half shady slopes and has a quadratic function relationship with the vegetation index on sunny and half sunny slopes, with the parabola moving upwards. The soil gravel content has a linear relationship with the vegetation index on shady and half shady slopes, and the image has a negative slope with a quadratic function relationship to the vegetation index on sunny slope and half sunny slope, with the parabola moving downwards. Due to differences among hydrothermal conditions, the relationship between vegetation coverage and soil quality indicators at different slope aspects is different; therefore, reasonable improvement of soil quality indicators on sunny and half sunny slopes could help plants to grow. These findings feed into a reference document that sets out how vegetation and soil quality may be improved in mining areas.

Effects of soil and topographic factors on vegetation restoration in opencast coal mine dumps located in a loess area.

Vegetation plays an important role in improving and restoring fragile ecological environments. In the Antaibao opencast coal mine, located in a loess area, the eco-environment has been substantially disturbed by mining activities, and the relationship between the vegetation and environmental factors is not very clear. Therefore, it is crucial to understand the effects of soil and topographic factors on vegetation restoration to improve the fragile ecosystems of damaged land. An investigation of the soil, topography and vegetation in 50 reclamation sample plots in Shanxi Pingshuo Antaibao opencast coal mine dumps was performed. Statistical analyses in this study included one-way ANOVA and significance testing using SPSS 20.0, and multivariate techniques of detrended correspondence analysis (DCA) and redundancy analysis (RDA) using CANOCO 4.5. The RDA revealed the environmental factors that affected vegetation restoration. Various vegetation and soil variables were significantly correlated. The available K and rock content were good explanatory variables, and they were positively correlated with tree volume. The effects of the soil factors on vegetation restoration were higher than those of the topographic factors.

Simulation and prediction of ion transport in the reclamation of sodic soils with gypsum based on the support vector machine.

The effect of gypsum on the physical and chemical characteristics of sodic soils is nonlinear and controlled by multiple factors. The support vector machine (SVM) is able to solve practical problems such as small samples, nonlinearity, high dimensions, and local minima points. This paper reports the use of the SVM regression method to predict changes in the chemical properties of sodic soils under different gypsum application rates in a soil column experiment and to evaluate the effect of gypsum reclamation on sodic soils. The research results show that (1) the SVM soil solute transport model using the Matlab toolbox represents the change in Ca(2+) and Na(+) in the soil solution and leachate well, with a high prediction accuracy. (2) Using the SVM model to predict the spatial and temporal variations in the soil solute content is feasible and does not require a specific mathematical model. The SVM model can take full advantage of the distribution characteristics of the training sample. (3) The workload of the soil solute transport prediction model based on the SVM is greatly reduced by not having to determine the hydrodynamic dispersion coefficient and retardation coefficient, and the model is thus highly practical.

Effect of byproducts of flue gas desulfurization on the soluble salts composition and chemical properties of sodic soils.

The byproducts of flue gas desulfurization (BFGD) are a useful external source of Ca(2+) for the reclamation of sodic soils because they are comparatively cheap, generally available and have high gypsum content. The ion solution composition of sodic soils also plays an important role in the reclamation process. The effect of BFGD on the soluble salts composition and chemical properties of sodic soils were studied in a soil column experiment. The experiment consisted of four treatments using two different sodic soils (sodic soil I and sodic soil II) and two BFGD rates. After the application of BFGD and leaching, the soil soluble salts were transformed from sodic salts containing Na2CO3 and NaHCO3 to neutral salts containing NaCl and Na2SO4. The sodium adsorption ratio (SAR), pH and electrical conductivity (EC) decreased at all soil depths, and more significantly in the top soil depth. At a depth of 0-40 cm in both sodic soil I and sodic soil II, the SAR, EC and pH were less than 13, 4 dS m(-1) and 8.5, respectively. The changes in the chemical properties of the sodic soils reflected the changes in the ion composition of soluble salts. Leaching played a key role in the reclamation process and the reclamation effect was positively associated with the amount of leaching. The soil salts did not accumulate in the top soil layer, but there was a slight increase in the middle and bottom soil depths. The results demonstrate that the reclamation of sodic soils using BFGD is promising.

Sodic soil properties and sunflower growth as affected by byproducts of flue gas desulfurization.

The main component of the byproducts of flue gas desulfurization (BFGD) is CaSO(4), which can be used to improve sodic soils. The effects of BFGD on sodic soil properties and sunflower growth were studied in a pot experiment. The experiment consisted of eight treatments, at four BFGD rates (0, 7.5, 15 and 22.5 t ha(-1)) and two leaching levels (750 and 1200 m(3) ha(-1)). The germination rate and yield of the sunflower increased, and the exchangeable sodium percentage (ESP), pH and total dissolved salts (TDS) in the soils decreased after the byproducts were applied. Excessive BFGD also affected sunflower germination and growth, and leaching improved reclamation efficiency. The physical and chemical properties of the reclaimed soils were best when the byproducts were applied at 7.5 t ha(-1) and water was supplied at 1200 m(3)·ha(-1). Under these conditions, the soil pH, ESP, and TDS decreased from 9.2, 63.5 and 0.65% to 7.8, 2.8 and 0.06%, and the germination rate and yield per sunflower reached 90% and 36.4 g, respectively. Salinity should be controlled by leaching when sodic soils are reclaimed with BFGD as sunflower growth is very sensitive to salinity during its seedling stage.

Nerve-root injections for the relief of pain in patients with osteoporotic vertebral fractures.

We have studied 58 patients with pain from osteoporotic vertebral fractures which did not respond to conservative treatment. These were 53 women and five men with a mean age of 72.5 years. They received a nerve-root injection with lidocaine, bupivicaine and DepoMedrol. The mean follow-up period was 13.5 months. The mean pain scores before treatment, at one and six months after treatment and at the final follow-up were 85, 24.9, 14.1, and 17.4, respectively. According to our modified criteria for grading results, six patients were considered to have an excellent result, 42 good and ten fair. A newly developed compression fracture was noted in three patients. There were no complications related to the injection. Our study suggests that nerve-root injections are effective in reducing pain in patients with osteoporotic vertebral fractures and that these patients should be considered for this treatment before percutaneous vertebroplasty or operative intervention is attempted.