Source contribution analysis of nutrient pollution in a P-rich watershed: Implications for integrated water quality management.

It is still a great challenge to address nutrient pollution issues caused by various point sources and non-point sources on the watershed scale. Source contribution analysis based on watershed modeling can help watershed managers identify major pollution sources, propose effective management plans and make smart decisions. This study demonstrated a technical procedure for addressing watershed-scale water pollution problems in an agriculture-dominated watershed, using the Dengsha River Watershed (DRW) in Dalian, China as an example. The SWAT model was improved by considering the constraints of soil nutrient concentration, i.e., nitrogen (N) and phosphorus (P), when modeling the nutrient uptake by a typical crop, corn. Then the modified SWAT model was used to quantify the contributions of all known pollution sources to the N and P pollution in the DRW. The results showed that crop production and trans-administrative wastewater discharge were the two dominant sources of nutrient pollution. This study further examined the responses of nutrient loss and crop yield to different fertilizer application schemes. The results showed that N fertilizer was the limiting factor for crop yield and that excessive levels of P were stored in the agricultural soils of the DRW. An N fertilizer application rate of approximately 40% of the current rate was suggested to balance water quality and environmental protection with crop production. The long-term impact of legacy P was investigated with a 100-year future simulation that showed the crop growth could maintain for 12 years even after P fertilization ceased. Our study highlights the need to consider source attribution, fertilizer application and legacy P impacts in agriculture-dominated watersheds. The analysis framework used in this study can provide a scientifically sound procedure for formulating adaptive and sustainable nutrient management strategies in other study areas.

Spatial characteristics of total phosphorus loads from different sources in the Lancang River Basin.

Lancang River, the upstream reach of Mekong River, is a hotspot region in the sustainable management of water resources and environment as it is currently facing the deterioration of aquatic ecosystems. Nutrient balance (i.e., Phosphorus) in the Lancang-Mekong River Basin has become a highly disputed issue in recent years due to the construction of cascade hydropower stations. However, the estimation of the total phosphorus (TP) load faces great difficulties and challenges due to the absent measured water quality data. This study estimates the TP load based on the social economic data, analyzes the spatial distribution of TP and the contribution of different TP sources in the Lancang River basin under the level of social-economic development in 2014. Results show that the annual average TP load in the Lancang River Basin is 1.6 × 104-3.9 × 104 tons, which is at a very low level compared with other large-scale basins in China. The TP load from natural soil erosion dominates all other sources, accounting for 69%, followed by agricultural production and fertilization. In general, the TP load increases from upstream to downstream, but heterogeneity also exits in different regions under the influence of various factors, such as rainfall intensity, soil properties and human activities. The results reveal a holistic picture of TP load in the Lancang River Basin, which could provide a new perspective on the trans-border international river management.