Design, synthesis, and application of thermally responsive draw solutes for sustainable forward osmosis desalination: A review.

Forward osmosis (FO) is an emerging sustainable desalination technology; however, it is not a stand-alone process and requires an additional step to recover the water or regenerate the draw solute (DS), making it energy extensive. Therefore, incorporating inexpensive energy sources for DS regeneration is a viable solution to compete with reverse osmosis desalination technology. Hence, selecting suitable DS and its regeneration became a crucial research focus in FO desalination. Among various DSs reported, thermally responsive DSs (TRDS) provide an opportunity to integrate low-grade energy sources for DS regeneration. Utilizing such inexpensive energy will reduce fossil fuel energy demand, lower the cost of desalination, and minimize the carbon footprint. Hence, this review explores the TRDS for FO-based desalination with its design, synthesis, and applications. The manuscript has discussed the classification and selection criteria for the DSs, and how traditional and new-generation TRDSs are designed and synthesized from cationic and anionic moieties of ionic liquids, hydrogels, and other chemicals. The manuscript has also given importance to design criteria such as osmotic strength, viscosity, toxicity, and thermal stability for TRDSs. Furthermore, a detailed discussion on the FO performance, energy, and economic aspects of TRDSs has been reviewed, along with a discussion on the possible low-grade energy sources for the recovery of TRDS. Finally, the challenges and future directions for TRDSs have been discussed to drive FO toward sustainable desalination technology.

Laser-induced graphene-based electrochemical biosensors for environmental applications: a perspective.

Biosensors are miniaturized devices that provide the advantage of in situ and point-of-care monitoring of analytes of interest. Electrochemical biosensors use the mechanism of oxidation-reduction reactions and measurement of corresponding electron transfer as changes in current, voltage, or other parameters using different electrochemical techniques. The use of electrochemically active materials is critical for the effective functioning of electrochemical biosensors. Laser-induced graphene (LIG) has garnered increasing interest in biosensor development and improvement due to its high electrical conductivity, specific surface area, and simple and scalable fabrication process. The effort of this perspective is to understand the existing classes of analytes and the mechanisms of their detection using LIG-based biosensors. The manuscript has highlighted the potential use of LIG, its modifications, and its use with various receptors for sensing various environmental pollutants. Although the conventional graphene-based sensors effectively detect trace levels for many analytes in different applications, the chemical and energy-intensive fabrication and time-consuming processes make it imperative to explore a low-cost and scalable option such as LIG for biosensors production. The focus of these potential biosensors has been kept on detection analytes of environmental significance such as heavy metals ions, organic and inorganic compounds, fertilizers, pesticides, pathogens, and antibiotics. The use of LIG directly as an electrode, its modifications with nanomaterials and polymers, and its combination with bioreceptors such as aptamers and polymers has been summarized. The strengths, weaknesses, opportunities, and threats analysis has also been done to understand the viability of incorporating LIG-based electrochemical biosensors for environmental applications.