Synthesis of quercetin-iron (Fe) complex and its in silico and in vitro confirmation towards antibacterial activity.

Aim: In this study quercetin-iron complex (QFC) was synthesized, and the structural characterizations such as x-ray diffraction, field emission-scanning electron microscopy, energy-dispersive x-ray and Brunner-Emmitt-Teller adsorption-desorption isotherm analysis revealed the crystallinity state, surface morphology and nature of the adsorbing surface with surface area value. Methodology: Functional characterizations such as UV-visible spectrometric and Fourier transform infrared analysis collectively indicated the chemical changes that appeared after complex formation in terms of characteristic change in the spectrum and band position, respectively. Results: The in vitro antibacterial activity against Escherichia coli and Staphylococcus aureus has shown a dose-dependent decrease in colony count and achieved significant removal at 15 mg/ml concentration of QFC. Conclusion: The molecular docking study supports the therapeutic application of QFC.

Experimental study of thermal characteristics of ZrO2/EG nanofluid for application of heat transfer.

In thermal management system, nanofluids will act as robust elements in future for coolants. Nanofluids have remarkable potential during the heat transfer increase reported by researchers from all over the world. Nanofluids have attracted many researchers, and there have been tremendous advances because of the high thermal characteristics and possible applications in certain areas such as the transport sector, aerospace, medical regions, and microelectronics. This current study reports on the thermal characteristics of nanofluid based on ZrO2/EG. The nanoparticles are characterized by XRD and SEM techniques. Nanofluid was prepared by a two-step method in ethylene glycol (EG) using ultra sonication. The thermal conductivity of ZrO2/EG nanofluid was investigated experimentally at various volume concentrations (0.02-0.1vol. %) and temperature range between 35 and 55 °C. The enhancement in thermal conductivity was observed to be 26.2% at 0.1 vol. % which exhibits superior performance as compared to base fluid (EG). The results of the experiment were compared with the three most often utilized model in the literature. The behavior of ZrO2/water-based nanofluid thermal conductivity, viscosity, and stability in various concentrations was studied.

ZrO2@chitosan composite for simultaneous photodegradation of three emerging contaminants and antibacterial application.

Emerging contaminants (ECs) are often detected in water bodies due to their prevalent use combined with inefficiency of the conventional wastewater treatment plants for their complete removal. Elimination of ECs using photocatalysis as a tertiary treatment can be a sustainable option for the reuse wastewater. Reported herewith is a photocatalyst, chitosan-based zirconia hybrid composite (ZrO2CTS-HC) for the individual/ simultaneous degradation of multiple ECs like Congo red (CR), Methyl orange (MO) and 4-hydroxybenzoic acid (4-HA) under visible light irradiation. Successfully synthesized ZrO2CTS-HC as confirmed by theoretical and various characterization techniques depicted photodegradation efficiency of 91.11, 69.11 and 78.40% for CR, MO and 4-HA respectively (SD 0.5-0.95; HPLC) aided by the reactive hydroxyl radical. Probable degradation mechanism supported by LC-MS/MS, COD and TOC along with reusability and antibacterial ability towards E.Coli & S.aureus is also reported. ZrO2CTS-HC can be a good option for elimination of residual ECs during tertiary treatment.

Antioxidant analysis of ultra-fast selectively recovered 4-hydroxy benzoic acid from fruits and vegetable peel waste using graphene oxide based molecularly imprinted composite.

Food processing industries generate 25-30% of fruit and vegetable peel (F&VP) waste of the total produce, which are rich in polyphenolic antioxidants (PA). Sustainable solution for the above waste can be its valorization for the recovery of PA, often used as natural preservative. Present work reports rationally designed graphene oxide-based molecularly imprinted composites (GOMIPs) using ionic liquid 1-allyl-3-octylimidazolium chloride (A) as a green functional monomer for selective recovery of PA 4-Hydroxy benzoic acid (4HA) from F&VP/pomegranate peel (PGP) waste. GOMIP-A and GOMIP-V were characterized using various techniques for its successful synthesis. GOMIP-A attained equilibrium within 10 min with adsorption capacity of 190.56 µmol g-1 for 4HA. Developed HPLC method depicted selective recovery of 77.23% and 62.83% 4HA from F&VP and PGP waste respectively by GOMIP-A. Subsequently, desorbed 4HA from GOMIP-A matrices exhibited the antioxidant potential of 33.53% (F&VP extract) and 47.97% (PGP extract) for DPPH radical.

Synthesis, characterization and optical property investigation of CdS nanoparticles.

Microwave-assisted routes have attracted much attention for nanoparticle synthesis because of minimal solvent use and rapid, high efficiency and controlled morphology. Cadmium sulphide (CdS) nanoparticles form the line between bulk and molecular states of materials and show variation in their physical and chemical properties. Cadmium sulphate and thiourea were used as precursors during this synthesis. These are included in the category of practical semiconductor metal sulphides, which are extensively used as catalysts and optical materials. X-ray diffraction (XRD) patterns confirmed that CdO nanoparticles are crystalline and have a hexagonal phase with crystal sizes that agree with transmission electron microscopy (TEM) data. UV-visible spectroscopy and photoluminescence (PL) spectroscopy were used to evaluate optical properties using band gap energy measurements.