Electrochemical detection of enrofloxacin in meat using bimetallic organic framework-derived NiCo2O4@NiO.

A novel electrochemical aptasensor based on a bimetallic organic frame-derived carbide nanostructure of Co and Ni (NiCo2O4@NiO) was prepared for rapid and sensitive enrofloxacin (ENR) detection of sheep and pork liver meats. The composite was fabricated by solvothermal and direct pyrolysis methods and dropped onto a modified electrode to improve the electron transfer efficiency. Furthermore, different techniques such as scanning electron microscopy and X-ray photoelectron spectroscopy were used to characterize the morphology and structure of the materials. Electrochemical impedance spectroscopy and cyclic voltammetry were used to evaluate the performance of the electrochemical sensor. As a result, the electrochemical aptasensor based on NiCo2O4@NiO exhibited excellent sensing performances for ENR with an extremely low detection limit of 1.67 × 10-2 pg mL-1 and a broad linear range of 5 × 10-2 to 5 × 104 pg mL-1, as well as great selectivity, excellent reproducibility, high stability and applicability. In addition, the relative standard deviation for real samples was in the range of 93.83 to 100.09% and 94.95 to 100.01% for sheep and pork liver. The results showed that the composite can be expected to greatly facilitate ENR detection and practical applications in harmful food due to the advantages of simple fabrication, controllable, large-area uniformity, environmental friendliness, and trace detection.

A new sensor for the rapid electrochemical detection of ractopamine in meats with high sensitivity.

In this research, g-C3N4/Cu@CoO/NC, which contained graphitic phase carbon nitride (g-C3N4) with a binary nanostructure and Cu@CoO/NC with a bimetallic MOF precursor, was constructed by a low-temperature pyrolysis process. The g-C3N4/Cu@CoO/NC was characterised by several techniques, including X-ray diffraction, scanning electron microscope, transmission electron microscope and X-ray photoelectron spectroscopy. Further, it was used to prepare an electrochemical sensor for the detection of ractopamine (RAC) in meat samples. The sensor showed excellent electrochemical oxidation characteristics for RAC detection, with a wide linear range (0.005 µmol/L to 32.73 µmol/L) and low detection limit (1.53 nmol/L). Meanwhile, the reproducibility, stability and interference of the g-C3N4/Cu@CoO/NC/GCE sensor were found to be excellent. Besides, the g-C3N4/Cu@CoO/NC/GCE sensor was well-used for the detection of RAC in pork, pig liver and lamb samples with recovery rates ranging from 96.5 % to 102.2 %.

Experimental study on the thermal characteristics of urban mockups with different paved streets.

Pavements in urban area absorb more sunlight due to the canyon-like geomorphology of the urban geometry and store more heat due to the great thermal bulk properties of concrete. Heat released from pavements warms up the urban air, contributing to the urban heat island. Recently, the uses of cool pavements to reduce the pavement temperature as an urban heat island mitigation have gained momentum. Understanding the temperature and solar insolation of a pavement in an urban area is important to adopt the right cool pavement option for the right place. This study measured the temperature of paved streets in an urban mockup for 4 days in summer. It is found that east-west (EW) streets are the hottest place in an urban area, followed by the intersection, and finally the south-north (SN) street and that increasing the pavement's albedo reduces the pavement temperature effectively. The dark gray pavement in an open space is hotter than that in an urban canyon. The heat storage in the building blocks keeps the pavement warmer more than 2 °C at nighttime. The EW street is exposed to solar insolation for long hours, so it is suitable for preferentially developing reflective cool pavements.