ABSTRACT
In the title compound, [Ir(C(13)H(9)N(4))(C(13)H(8)NS)(2)]·3.5CDCl(3), the coordination at iridium is octa-hedral, but with narrow ligand bite angles. The bond lengths at iridium show the expected trans influence, with the Ir-N bonds trans to C being appreciably longer than those trans to N. The chelate rings are mutually perpendicular, the inter-planar angles between them all lying within 6° of 90°. All ligands are approximately planar; the maximum inter-planar angles within ligands are ca 10°. The three ordered deuterochloro-form mol-ecules are all involved in Câ¯D-A contacts that can be inter-preted as hydrogen bonds of various types. The fourth deuterochloroform is disordered over an inversion centre.
ABSTRACT
In the title compound, [Ir(C(11)H(6)F(2)N)(2)(C(22)H(17)N(4)O)]·CH(3)OH, the coordination at iridium is essentially octa-hedral, but with distortions associated with the bite angles of the ligands [76.25â (9)-80.71â (12)°] and the differing trans influences of C and N ligands [Ir-N = 2.04â Å (average) trans to N but 2.14â Å trans to C]. All three bidentate ligands have coordinating ring systems that are almost coplanar [inter-planar angles = 1.7â (1)-3.8â (2)°]. The vinyl-benzyl group is disordered over two positions with occupations of 0.653â (4) and 0.347â (4). The methanol solvent mol-ecule is involved in a classical O-Hâ¯N hydrogen bond to a triazole N atom.