ABSTRACT
Back-gated InAs nanowire field-effect transistors are studied focusing on the formation of intrinsic quantum dots, i.e. dots not intentionally defined by electrodes. Such dots have been studied before, but the suggested explanations for their origin leave some open questions, which are addressed here. Stability diagrams of samples with different doping levels are recorded at electron temperatures below 200 mK, allowing us to estimate the number and size of the dots as well as the type of connection, i.e. in series or in parallel. We discuss several potential physical origins of the dots and conclude that they are most probably induced by potential fluctuations at the nanowire surface. Additionally, we show that via gate voltage and doping, the samples can be tuned to different regimes of Coulomb blockade.
ABSTRACT
The Tp ligand tris(3-cumenyl-5-methylpyrazolyl)borate was found to stabilize zinc complexes of nucleobases, of their natural precursors, and of nucleoside and nucleotide derivatives. Dihydroorotic acid and orotic acid are bound as monodentate carboxylate ligands. Uracil is coordinated via its deprotonated N1; 6-methylthiouracil acts as a bidentate ligand via N1 and S. Analogously, xanthine is a monodentate ligand bound by its deprotonated N7, while 6-mercaptopurine seems to bind in a bidentate fashion via N7 and S. Spectroscopic evidence indicates coordination of uridine and 2',3'-O-isopropylideneuridine via their deprotonated N3, as well as of xanthosine via N7. The hydrolytic cleavage of 2',3'-O-isopropylideneuridine 5'-(bis(p-nitrophenyl) phosphate) by TpZn-OH is preceded by an attachment of one TpZn unit to the deprotonated uracil base, presumably via N3.
