ABSTRACT
Achieving high-efficiency thick-film bulk heterojunction (BHJ) organic solar cells (OSCs) with thickness-independent power conversion efficiencies (PCEs) in a wide thickness range is still a challenge for the roll-to-roll printing techniques. The concept of diluting the transport sites within BHJ films with insulating polymers can effectively eliminate charge trapping states and optimize the charge transport. Herein, we first adopted the concept with insulating polypropylene (PP) in the efficient non-fullerene system (PM6:Y6) and demonstrated its potential to fabricate thick-film OSCs. The PP can form an insulating matrix prior to PM6 and Y6 within the BHJ film, resulting in an enhanced molecular interaction and isolated charge transport by expelling Y6 molecules. We thus observed reduced trap state density and improved charge transport properties in the PP-blended device. At around 300 nm, the PM6:Y6:PP device enjoys a high PCE of 15.5% and achieves over 100% of the efficiency of the optimal thin-film device, which is significantly improved compared to the binary PM6:Y6 counterpart. This research promotes an effective strategy with insulating polymers and provides knowledge of commercial production with response to the roll-to-roll technique demands.
ABSTRACT
Organic photovoltaic (OPV) cells have found their potential applications in the harvest of indoor light photons. However, the output power of such indoor devices is usually far from the demand of the internet of things. Therefore, it is essential to boost the output power of indoor organic photovoltaics to a much higher level. As wildly deployed among industrial and civil luminous environments, thermal radiation-based indoor light sources are alternative candidates to supply the essential power of the off-grid electronics with a broad consecutive emission spectrum. In this work, we evaluated the photovoltaic performance of organic solar cells under indoor incandescent and halogen illuminations. Impressively, under such thermal radiations, an improvement over 500% of the output power density can be achieved in comparison with that under light-emitting diodes and fluorescent lamps, reaching a record high value of 279.1 µW cm-2 by the PM6:Y6-based device. The remarkable power output is originated from the extra near-infrared spectrum of indoor thermal lights, which restricts the effective area under 10 cm2 in achieving 1 mW output power. This work clarifies the feasibility of collecting photons radiated from indoor thermal light sources through OPV cells, and enlightens the further applications of indoor OPV cells under multiple illumination environments.
ABSTRACT
The surface plasmon resonance (SPR) of metallic nanomaterials, such as gold (Au) and silver (Ag), has been extensively exploited to improve the optical absorption, the charge carrier transport, and the ultimate device performances in organic photovoltaic cells (OPV). With the incorporation of diverse metallic nanostructures in active layers, buffer layers, electrodes, or between adjacent layers of OPVs, multiple plasmonic mechanisms may occur and need to be distinguished to better understand plasmonic enhancement. Steady-state photophysics is a powerful tool for unraveling the plasmonic nature and revealing plasmonic mechanisms such as the localized surface plasmon resonance (LSPR), the propagating plasmon-polariton (SPP), and the plasmon-gap mode. Furthermore, the charge transfer dynamics in the organic semiconductor materials can be elucidated from the transient photophysical investigations. In this review article, the basics of the plasmonic mechanisms and the related metallic nanostructures are briefly introduced. We then outline the recent advances of the plasmonic applications in OPVs emphasizing the linkage between the photophysical properties, the nanometallic geometries, and the photovoltaic performance of the OPV devices.
