Temperature-dependent near-surface interstitial segregation in niobium.

Niobium's superconducting properties are affected by the presence and precipitation of impurities in the near-surface region. A systematic wide-temperature range x-ray diffraction study is presented addressing the effect of low temperatures (108 K-130 K) and annealing treatments (523 K in nitrogen atmosphere, 400 K in UHV) on the near-surface region of a hydrogen-loaded Nb(100) single-crystal. Under these conditions, the response of the natural surface oxides (Nb2O5, NbO2, and NbO) and the changes in the subsurface concentration of interstitial species in Nb are explored, thereby including the cryogenic temperature regime relevant for device operation. The formation and suppression of niobium hydrides in such conditions are also investigated. These treatments are shown to result in: (i) an increase in the concentration of interstitial species (oxygen and nitrogen) occupying the octahedral sites of the Nb bcc lattice at room temperature, both in the near-surface region and in the bulk. (ii) A decrease in the concentration of interstitials within the first 10 nm from the surface at 130 K. (iii) Hydride formation suppression at temperatures as low as 130 K. These results show that mild annealing in nitrogen atmosphere can suppress the formation of superconducting-detrimental niobium hydrides, while subsurface interstitial atoms tend to segregate towards the surface at 130 K, therefore altering the local concentration of impurities within the RF penetration depth of Nb. These processes are discussed in the context of the improvement of niobium superconducting radio-frequency cavities for next-generation particle accelerators.

Vacancy-Hydrogen Interaction in Niobium during Low-Temperature Baking.

A recently discovered modified low-temperature baking leads to reduced surface losses and an increase of the accelerating gradient of superconducting TESLA shape cavities. We will show that the dynamics of vacancy-hydrogen complexes at low-temperature baking lead to a suppression of lossy nanohydrides at 2 K and thus a significant enhancement of accelerator performance. Utilizing Doppler broadening Positron Annihilation Spectroscopy, Positron Annihilation Lifetime Spectroscopy and instrumented nanoindentation, samples made from European XFEL niobium sheets were investigated. We studied the evolution of vacancies in bulk samples and in the sub-surface region and their interaction with hydrogen at different temperature levels during in-situ and ex-situ annealing.