The emergence of 3D-printed firearms: An analysis of media and law enforcement reports.

3D-printed firearms, an emerging category of privately made firearms (PMF) produced beyond government control, have become increasingly prevalent due to technological advancements. They are now emerging as a cost-effective and reliable alternative to conventional firearms. Raised to public awareness following the 2013 release of the 3D-printed Liberator, these firearms are now more commonly encountered by police forces. This article analyses various reports involving 3D-printed firearms, reflecting the increasing encounters by law enforcement agencies. It examines 186 cases involving 3D-printed firearms, primarily from North America, Europe, and Oceania, highlighting a significant rise in incidents since 2021. These incidents include seizures, illicit uses, and online sales, with the firearms typically being hybrid models, Parts Kit Completions/Conversions (PKC), or firearm components such as auto sears. The study underscores the use of affordable equipment and materials for production, emphasizing the accessibility and potential risks of these firearms.

Investigating the availability of 3D-printed firearm designs on the clear web.

The release of the plans of the 3D-printed Liberator firearm sparked a wave of new designs from creators worldwide, resulting in an extensive collection of 3D-printed firearm plans, in particular blueprints, and parts available for almost unrestricted download on the internet. Identifying and categorizing the diverse range of 3D-printed firearms and components pose a challenge due to the abundance of designs available. Between 2021 and April 2023, data was collected on over 2,100 3D-printed firearm plans. While blueprints of fully 3D-printed firearms initially dominated the scene, hybrid designs and parts kit completions / conversions (PKC) have gained popularity for their improved reliability and performance. The now highly networked community offers considerable support with detailed instructions and procedures, providing precise guidance for construction. This systematic classification, grouping and structuration of the recorded data on the Clear Web supported the identification of patterns of the main threat trends related to 3D-printed firearms.

Technical note: Influence of the drying position and time on the persistence of gunshot residues on fabrics.

The influence of the drying position and time on the persistence of gunshot residues (GSR) on fabrics was investigated. Powder tattooing from a 40 cm shooting distance on targeted fabrics were slightly wetted using a spray and dried for 3 h or 48 h in horizontal or vertical positions. The GSR particles were visualised using IR fluorescence with a Video Spectral Comparator (VSC) and automatically counted with a software before the wetting and after the drying stages. While a significant rate of GSR particles (up to 22%) were lost, it was mainly due to the wetting procedure rather than the drying stage. No statistically significant difference was observed between the drying positions, indicating that both drying positions can be used in practice to dry slightly wet fabrics. The drying time had no influence on the loss, and the GSR distribution was not significantly influenced by either factor (i.e., time and position).

Cleaning deteriorated elements of ammunition: Development of a procedure applied to cartridge cases from the Second World War.

Deteriorated elements of ammunition can be found while investigating different types of events. Exposure to adverse environmental conditions may lead to metal alteration (corrosion) or organic material deposition (contaminations) on the exposed elements of ammunition. From a forensic perspective, both types of deterioration pose challenges when observing marks left by the firearms used to discharge the corresponding ammunition (e.g. firing pin, extractor). The longer the time of exposure to the adverse environmental conditions, the more challenging the observation of such marks. A literature review highlighted three previously published restorative methods used to clean deteriorated elements of ammunition. The aim of this research is to develop a cleaning procedure applicable to cartridge cases exposed to adverse environmental conditions, while avoiding the degradation of marks left by the firearms used to discharge the corresponding ammunition. A first batch of 21 brass cartridge cases dating back to the Second World War (WWII) was used to develop a cleaning sequence involving the three methods. The efficiency of each restorative method was qualitatively assessed using optical macroscopy and the Evofinder® ballistic identification system. The developed sequence relies on successive applications of Tickopur® TR 7 (a diluted soft metal cleaner), sulfuric acid and finally Aqua Regia (HCl 37% and HNO3 75%), all of them involving ultrasonic baths. The resulting cleaning sequence was subsequently applied to three batches of Second World War cartridge cases discovered in France and Russia. This sequential procedure allows the effective cleaning of WWII brass cartridge cases while highlighting different marks left by firing pins, extractors, ejectors, and breech faces. Applying a forensic analysis and comparison process to the marks highlighted on these elements of ammunition can support the verification of historical facts when reconstructing events which took place more than seventy years ago.

Was a 3D-printed firearm discharged? Study of traces produced by the use of six fully 3D-printed firearms.

Since the blueprints of the Liberator were published and successfully tested, countless new designs for said 3D-printed firearms and 3D-printed firearm components have been created and made publicly available. These new 3D-printed firearms, which are praised by their designers as ever more reliable, can be found on the Internet with little effort. Press reports have shown that various models of 3D-printed firearms have already been confiscated by law enforcement services around the world. So far, forensic studies have addressed this set of problems relatively little, whereby for the most part only the Liberator has been examined in detail and three other designs were only included a few times. The rapid pace of this development poses new challenges for forensic investigations and unveil new spheres of investigation regarding 3D-printed firearms. This research initiative aims to determine whether the results from previous studies on Liberators, are also reproducible and observable when using other models of 3D-printed firearms. In this respect six fully 3D-printed firearms - PM422 Songbird, PM522 Washbear, TREVOR, TESSA, Marvel Revolver and Grizzly - were produced on a material extrusion type Prusa i3 MK3S using PLA as the material. Test firings of these 3D-printed firearms have shown that they are indeed functional, but that, depending on the model, they suffer different levels of damage when fired. However, they were all rendered inoperative after one discharge and could not be used for further discharges unless the broken pieces were replaced. As in other studies, the firing process and the resulting ruptures on the 3D-printed firearm, projected polymer parts and fragments of different sizes and in different quantities into the immediate environment. The parts could be physically matched, allowing the reconstruction and identification of the 3D-printed firearms. Elements of ammunition also showed traces of melted polymer on the surface and cartridge cases bore tears or swellings.

Comprehensive Characterization of Shredded Lithium-Ion Battery Recycling Material.

Herein we report on an analytical study of dry-shredded lithium-ion battery (LIB) materials with unknown composition. Samples from an industrial recycling process were analyzed concerning the elemental composition and (organic) compound speciation. Deep understanding of the base material for LIB recycling was obtained by identification and analysis of transition metal stoichiometry, current collector metals, base electrolyte and electrolyte additive residues, aging marker molecules and polymer binder fingerprints. For reversed engineering purposes, the main electrode and electrolyte chemistries were traced back to pristine materials. Furthermore, possible lifetime application and accompanied aging was evaluated based on target analysis on characteristic molecules described in literature. With this, the reported analytics provided precious information for value estimation of the undefined spent batteries and enabled tailored recycling process deliberations. The comprehensive feedstock characterization shown in this work paves the way for targeted process control in LIB recycling processes.

Influence of cell opening methods on organic solvent removal during pretreatment in lithium-ion battery recycling.

The use and development of lithium-ion batteries (LIBs) are promoting the technological transformation of individual mobility, consumer electronics and electric energy storage. At their end of life, the complex compounds are disposed by different recycling technologies with defined secondary raw material production. The applied depollution temperatures of the process routes influence not only the recycling efficiency but also the process expenditure, design, medium and costs. Different pretreatment strategies in terms of dismantling depth and depollution temperature are existing. Furthermore, manual and mechanical methods for cell opening are distinguished, which together with the depollution leads to a respective organic solvent evaporation. In this contribution to LIB recycling, the influence of different dismantling depths, achieved by manual cell opening, on the thermal depollution of the LIB cells regarding the mass difference originating by organic solvent evaporation are quantified, in order to determine cell and equipment properties for a safe cell opening. As a result, combinations of thermal depollution and manual cell opening are discussed regarding technical and economic feasibility. The process medium and equipment properties for a safe cell opening are determined. Furthermore, recommendations for future industrial LIB waste management are presented.

Monitoring illicit ammunition through the ballistic datasets of four European countries.

Few countries systematically record and publish detailed information on the types, caliber, and makes of ammunition recovered by law enforcement. This results in a lack of knowledge of the ammunition used in crime, including in the European context. This pilot study examines the utility of ballistic datasets for monitoring illicit ammunition. The ballistic laboratories of four European countries-Denmark, Germany, Sweden, and Switzerland-provided access to non-confidential subsets of their national databases, including the caliber of recovered cartridge cases as well as the year and type of incident in which they were used. The laboratories also shared images of the ammunition headstamp markings, which helped determine each cartridge case's manufacturer and-when known-year of production. The resulting dataset covers 3130 cartridge cases documented by the participating laboratories between 2015 and the first quarter of 2020. Although limited in scope-the research team did not have access to geocoded data so spatial comparisons were limited to the country level-the dataset helps generate a baseline of the main varieties of ammunition used in crime, by country and crime category, and over time. Most of the ammunition (61 per cent) was recovered in the context of violent types of crime-homicides and assaults-for which pistol ammunition calibers were the most prominent. 610 unique headstamps were recorded, but only a small proportion of these varieties of ammunition accounted for most of the cases. All four country datasets included both foreign-made ammunition as well as cartridges produced domestically. The year of manufacture could be identified for 28 per cent of the cartridges, and at least 27 pieces of ammunition were produced in the same year that the criminal incident took place, which suggests recent diversion from licit holdings. The dataset revealed additional trends such as the criminal use of blank ammunition in all four case studies, as well as the relatively new prevalence of the 7,62 × 39 caliber-which is typically used with AK-pattern rifles-in one country. In addition to shedding new light on the types of ammunition used in crime in the European context, monitoring illicit ammunition across space and over time has the potential to support police investigations with intelligence on criminals' sources of supply.

Influence of the printing process on the traces produced by the discharge of 3D-printed Liberators.

Since its introduction in 1986, 3D printing technology is in constant development. 3D printers are becoming more and more performant and accessible. In 2013, the Liberator blueprints are released online. This single-shot pistol can be entirely manufactured using a 3D printer, except for the firing pin and the ammunition. First, this research aims at establishing an overview of all the elements and traces potentially present when a 3D-printed firearm is involved, whether it is fired or not. In the second part, we study these elements for exploitability to obtain information about the manufacture of the firearm (printing processes, 3D printers and polymers). For this purpose, a total of 36 Liberators were manufactured using different printing conditions (i.e., printing processes, printers, polymers and parameters). The tested printing processes were based on the principles of Material Extrusion (ME), Vat Photopolymerization (VP) and Powder Bed Fusion (PBF). All 3D-printed firearms manufactured via ME and PBF were able to fire whereas Liberators manufactured by VP printing could not be fired. This could be explained by the lack of precision of the prints making it impossible to assemble some of the Liberators, or by the fact that the polymer was not suitable to produce the springs. All the barrels were broken by the discharge, projecting polymer pieces or fragments into the environment. These polymer pieces or fragments were examined to determine which printing process was used as well as other elements related to printing parameters and conditions (e.g., layer height, filling pattern and infill density). This information is useful to determine whether a certain command file, slicer or 3D printer could be at the source of a questioned 3D-printed firearm. Melted polymer or polymer particles on elements of ammunition may also be present after the firing process. However, the examination of these particles does not allow inferring other information, except the possible use of a 3D-printed polymer firearm.

Detection of gasoline on suspects' hands: Study of different sampling alternatives.

Arsonists may use ignitable liquids to start, accelerate and amplify fires. The sampling of volatiles present on the hands of suspected arsonists is therefore sometimes carried out in the course of the investigation of (possible) deliberate fires. Several collection protocols have been proposed, relying on the concentration of volatiles by the transfer on PVC gloves and further passive headspace extraction with Activated Charcoal Strips (ACS). Previous research findings assessing the use of Activated Carbon Cloth (ACC) - initially developed for the adsorption of gas in military applications - opens the path to new perspectives regarding the extraction and the concentration of ignitable liquid residues in general, and for the sampling on hands in particular. Five alternative methods (four relying on the use of ACC and one on ACS) were considered for the collection of gasoline traces present on the hands and their subsequent analysis by gas chromatography - mass spectrometry. Gasoline was deposited onto the palms of volunteers to study the differences between the collection method using ACS and those using ACC. For the latter, either the volunteer hands were placed in nylon bags with an ACC on the palm or suspended, or, powder-free latex gloves were used, with an ACC on the palm or in a separate extraction, with the glove in a nylon bag and the ACC suspended. The results showed that the background contamination was not distinguishable between ACS and ACC and their sampling ability was comparable. The two methods relying on the deposition of ACC directly on the surface of the palm where gasoline was deposited showed significantly higher collection capacity than other methods, provided that the ACC was in direct contact with the contaminated zone. The results showed that three main factors affected the collection of gasoline on the hands: the distance between the skin and the sorbent (ACC or ACS) in case of direct concentration of volatiles on the sorbent, the exposure time, and the space between the hand and the glove or bag (i.e. the headspace volume). This research opens new perspectives for the sampling of ignitable liquid residues through the use of ACC. It corroborates the perceived potential of ACC for the extraction and concentration of volatile compounds, particularly for fire debris analysis purposes. While the experiments were focused on the collection of gasoline on hands, the results provide valuable information in a more general way for the sampling of fire debris.

Fibre persistence on static textiles under outdoor conditions.

The persistence of fibres under outdoor conditions is seldom investigated. This research aimed to study simultaneously the influence of several factors (and their cross-interactions) on the persistence of fibres on static textile surfaces. In order to achieve this aim, a design of experiments was successfully implemented under laboratory conditions. Four factors were considered: time, inclination of the recipient textile, wind speed, and rainfall. The model obtained by this supervised method was compared with the results collected under actual outdoor conditions near a weather station. The resulting model appears to be reliable as long as the values of the factors are kept within the range used in the study. The results of the laboratory tests showed that wind speed and rainfall significantly influence the persistence of fibres while time and inclination of the recipient textile have been found to be nonsignificant. In general, the observed persistence was high: between 90.4 and 100%. This might be attributed to the recipient textile surface possessing abundant protruding fibres which "traps" the transferred fibres. Outdoor experiments usually suffer from a higher variability and result in a higher fibre loss. In outdoor conditions, wind and rainfall have shown an extensive influence on the fibre persistence. Finally, the trend of fibre persistence on static textiles in outdoor conditions is generally linear with time, but extreme meteorological condition will induce exponential losses.

Combined Collection and Analysis of Inorganic and Organic Gunshot Residues.

Gunshot residue (GSR) analysis and their interpretation provide crucial information on a criminal investigation involving the use of firearms. To date, several approaches have been proposed for the implementation of a combined sampling and analysis of inorganic (IGSR) and organic GSR (OGSR). However, it is not clear at this stage if concurrent analyses of both types of residue might be detrimental to the analysis of IGSR currently applied in forensic laboratories. Thus, this work aims to compare and evaluate three different protocols for the combined collection and analysis of IGSR and OGSR. These methods, respectively, involve the use of a modified stub (with two halves, one for the detection of IGSR and the other for the analysis of OGSR); the sequential recovery of GSR with two stubs mounted with different adhesives (double-sided carbon tape and Tesa® TACK) and the sequential analysis of IGSR and OGSR from a single carbon stub following carbon deposition. The detection of IGSR was carried out using SEM-EDX, while OGSR analysis was performed using ultra-high-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS). Obtained results for experiments performed using Geco Sinoxid® ammunition indicated that sequential analysis was the most suitable protocol for the combined collection and analysis of both IGSR and OGSR. A higher number of inorganic (characteristic and consistent) particles and higher concentrations of ethylcentralite, N-nitrosodiphenylamine, diphenylamine, and nitroglycerin were recovered with this method.

Comparison of three collection methods for the sodium rhodizonate detection of gunshot residues on hands.

The aim of this study was to compare three gunshot residue (GSR) collection methods used in conjunction with chemographic detection applied by different regional Swiss police services. The specimens were collected from the hands of a shooter with either filter paper (Filter method) or adhesive foil. The adhesive foil was then either applied against photographic paper during visualisation (AF Photo method) or coated with a layer of polyvinyl alcohol (AF PVAL method). The experiments involved two conditions of the examined hands, i.e. dry and humidified. The residues were revealed using the sodium rhodizonate test (SRT). Preliminary tests assessing the possibility of conducting a confirmatory Scanning Electron Microscopy coupled to Energy Dispersive X-ray spectroscopy (SEM/EDX) analysis after the chemographic test were performed on a number of specimens by cutting positive spots and mounting them on stubs. Obtained results were compared in terms of effectiveness - number of positive spots, time requirements, quality of subsequent SEM-EDX analysis, ease of use and cost. The Filter method generally yielded a high-quality detection with both dry and humidified hands, as well as a simple, quick and efficient confirmation by SEM/EDX. The AF Photo performed well on dry hands, but not on humidified hands. The AF PVAL method performance was lower compared to the other methods in both examined conditions of the hands. The SEM/EDX analysis showed that the Filter and AF PVAL method provided satisfactory results when a sufficient carbon coating thickness was applied to the cuttings. It was also observed that the thinner the PVAL layer, the better the quality of the spectra and obtained images in SEM/EDX. Furthermore, the surface of the photographic paper did not seem to be conductive, even after the application of a thick layer of carbon. In conclusion, the Filter method gave the best overall results, but its application required slightly more time and expertise than the two other methods.

Identification of some factors influencing soil transfer on shoes.

In criminal activities, soil can be transferred from a crime scene to items linked with a perpetrator; for example, shoes, cars or tools. Several parameters will influence the quantity of soil transferred in a given scenario. The knowledge of the most influential factors can help the expert to assess the evidence using a logical approach at the activity level or to predict the amount of soil that can be expected in a given scenario. The influence of five chosen parameters, namely the shoe profile, shoe size, walker's weight, soil type and soil humidity were assessed using Design of Experiment (DOE) in order to understand their influence on soil quantity transferred on shoes. The Faced Central Composite Design (FCCD) using a quadratic model was found to be highly significant, thus they could be adequately used to model and to interpret the amount of soil recovered from one shoe. These designs demonstrate that the characteristics of the donor (soil type and soil humidity), as well as a combination of these two factors have a very significant impact on the soil transfer. The characteristics of the receptor (shoe profile, shoe size and walker's weight) also have an impact on the transfer but to a lesser extent. Globally, this research provides valuable information for the forensic scientist both in investigative mode: evaluation of the soil quantity possibly transferred on shoes, and in the evaluative steps: is the quantity of soil found on the suspect shoes in accordance to the proposition/scenario given by the prosecution and the defence?

How to recognise the traces left on a crime scene by a 3D-printed Liberator? Part 2. Elements of ammunition, marks on the weapons and polymer fragments.

The Liberator is a firearm that can be manufactured from its blueprints by the means of a 3D-printer. This handgun is composed of nineteen pieces: eighteen made of printed polymer and one metallic nail. This study focuses on the physical traces which can be found and exploited from a forensic point of view after the discharging of such types of pistols. Two main aspects have been investigated: (1) whether it can be inferred that a 3D-printed handgun was used when investigating a scene; (2) when presuming the use of a 3D-printed Liberator on a scene. Six Liberators were manufactured, assembled and discharged. The discharge occurred under controlled conditions to allow the collection of ballistics data and traces produced by the shooting. Elements of ammunition - cartridge cases and projectiles - that were fired during an experimental campaign appeared to carry polymeric materials (flakes, melted polymer or both). Besides, we observed that the fired ammunition elements lacked traditional marks left by the metal pieces of a conventional firearm. Indeed, the projectiles did not carry rifling marks and the cartridge cases were found torn or swollen. Fragments or larger pieces of polymer were found, mostly on the ground, near the location of the discharge, up to nine metres away. The impression of the cartridge case head stamp was also found on a part of the Liberator called the "hammer body". This study showed that the discharge of a 3D-printed Liberator is expected to produce traces that can be transferred onto and recovered from the printed firearm, the cartridge case, the projectile, the target, and the environment of the discharge. These traces are different from those left by conventional firearms. When found on investigation scenes, some of these traces can inform on the use of a 3D-printed handgun and contribute to the reconstruction of a shooting event involving such a weapon. This study suggests that the approach adopted when investigating a scene must be adapted in terms of traceology when the use of such firearm is suspected.

Secondary transfer of organic gunshot residues: Empirical data to assist the evaluation of three scenarios.

The present study aimed at providing data to assess the secondary transfer of organic gunshot residues (OGSR). Three scenarios were evaluated in controlled conditions, namely displacing a firearm from point A to point B, a simple handshake and an arrest involving handcuffing on the ground. Specimens were collected from the firearm, the hands of the shooter and the non-shooter undergoing the secondary transfer in order to compare the amounts detected. Secondary transfer was observed for the three scenarios, but to a different extent. It was found that displacing a firearm resulted in secondary transfer in <50% of the experiments. The firearm also had an influence, as contrary to the pistol, no secondary OGSR were detected using the revolver. Shaking the hand of the shooter also transferred OGSR to the non-shooter's hand. In that case, the amount of OGSR was generally higher on the shooter than on the non-shooter. Finally, the largest secondary transfer was observed after the arrest with handcuffing with positive results in all cases using the pistol. In that scenario, the amounts on the shooter and the non-shooter were in the same range. This study highlights that the secondary transfer must be taken into account in the interpretation of OGSR. Indeed, an individual's hands might be contaminated by handling a firearm or having physical contact with a shooter.

Comparison of three bullet recovery systems.

Comparing the marks left on questioned bullets to those left on reference bullets is the main aim of a firearm identification expertise. Thus, producing reference bullets with a questioned firearm is an essential step. Different kinds of system have been developed to safely recover bullets fired from questioned firearms. However, the performance of each system and its impact on traces left on the bullets have not been addressed. Three bullet recovery systems - a horizontal water tank, a cotton tube and a recently designed fleece - were used to fire seven types of ammunition of various type, shape and casing. The bullets were then described and images of their surface were acquired with an automatic system to study the impact of each system on the bullets. The water tank is the more efficient system in terms of quality of the marks. However, it cannot be used to fire every type of ammunition. Some of them, such those used by law enforcement, tend to be damaged with this system. A way to mitigate the problem is to use the cotton or the fleece-based systems, the latter being more universal. It requires a cleaning step to remove all the fibres from the surface of the bullet, but the marks left by the weapon are still of interest.

How to recognize the traces left on a crime scene by a 3D-printed Liberator?: Part 1. Discharge, exterior ballistic and wounding potential.

The Liberator is a firearm that can be manufactured from its blueprints, using a 3D-printer. This weapon made of nineteen pieces - eighteen in printed plastic and one metallic nail - raises questions such as its ability to fire a round, its wounding potential and the traces produced by its discharge. In particular, knowledge must be gained to infer that a 3D-printed handgun was used, reconstruct the shooting event involving such handgun, and gather information related to the type of 3D-printed handgun used. This study focused on the traces that could orientate forensic investigations when the use of a 3D-printed Liberator is suspected. In a first step, the Liberator was investigated to study its behaviour during the discharge and characterize traces produced by the discharge. To fulfil this goal, some Liberators were printed and assembled. Six Liberators fired a round. The discharge of the weapons was done under specific conditions allowing to collect ballistics data and traces produced by the shooting. The results showed that the barrel tended to break between the ignition of the primer and the moment the projectile exited the muzzle. The speed of the projectiles reached 140m/s when the barrel broke, while it was about 170m/s when barrel remained intact. The trajectory of the projectiles was sometimes disrupted, and the projectile tumbled on itself. It was thus very difficult to characterize the trajectory. The cavity wound caused by the fastest bullet was typical of a handgun wound firing a FMJ projectile (penetration of 21cm in ballistics soap). On the other hand, the cavity caused by the slowest bullet was more representative of a splinter wound (penetration of 14cm in ballistics soap). The study of gunshot residues collected on adhesive targets showed the presence of unburnt particles and small perforations caused by polymer pieces that concentrated around the entry holes.

Characterising the online weapons trafficking on cryptomarkets.

Weapons related webpages from nine cryptomarkets were manually duplicated in February 2016. Information about the listings (i.e. sales proposals) and vendors' profiles were extracted to draw an overview of the actual online trafficking of weapons. Relationships between vendors were also inferred through the analysis of online digital traces and content similarities. Weapons trafficking is mainly concentrated on two major cryptomarkets. Besides, it accounts for a very small proportion of the illicit trafficking on cryptomarkets compared to the illicit drugs trafficking. Among all weapon related listings (n=386), firearms only account for approximately 25% of sales proposal since the proportion of non-lethal and melee weapons is important (around 46%). Based on the recorded pseudonyms, a total of 96 vendor profiles were highlighted. Some pseudonyms were encountered on several cryptomarkets, suggesting that some vendors may manage accounts on different markets. This hypothesis was strengthened by comparing pseudonyms to online traces such as PGP keys, images and profiles descriptions. Such a method allowed to estimate more accurately the number of vendors offering weapons across cryptomarkets. Finally, according to the gathered data, the extent of the weapons trafficking on the cryptomarkets appear to be limited compared to other illicit goods.