ABSTRACT
Cryovolcanism has been invoked to explain numerous features observed on icy bodies. Many of these features show similar morphologies to volcanic features observed on Earth suggesting similar physics involved in their formation. Cryovolcanism lies at the intersection of volcanology and hydrology but as such, no one model from either discipline satisfactorily represents cryolava flow emplacement. We produced a new model for cryolava flow evolution that draws from both disciplines to track the physical, chemical, and thermal states of a hypothetical H2O-NaCl flow on a Europa-like body as it evolves away from the vent. This model is currently restricted to compositions on the water-rich side of this chemical system and only predicts emplacement up to the turbulent to laminar transition. Modeling the laminar regime and a broader compositional space will be dealt with separately. Concentrations between 5 and 23 wt% (H2O-NaCl eutectic) and initial flow thicknesses of 0.1, 1, 10, and 100 m were set as initial conditions. Model results suggest that flow may reach 40-60 vol% solids before transitioning to laminar flow. The thermal budget for these flows is dominated by the heat loss from vaporization in the low-pressure environment. This model produces length to thickness aspect ratios, for the given compositions, that are broadly consistent with candidate cryovolcanic features on Ceres and Titan. These first-order comparisons are not ideal and suggest the need for future modeling of cryovolcanic features in at least two dimensions.
ABSTRACT
Thermotropic polymers with the capability of thermally tuning transparency are widely applied in smart windows and energy-saving windows, playing a critical role in enhancing comfort level and energy efficiency of indoor spaces. Usually, thermotropic polymer systems are constructed by physically dispersing phase transition materials in transparent hosting materials. However, bad interfaces universally exist in these systems, resulting in poor mechanical properties, weak interfaces to substrates, or bad long-term stability. Herein, we demonstrate a novel chemically interconnected thermotropic polymer, which is obtained by reacting dodecanedioic acid (DDA) with glycerol. In the system, some of DDA molecules were cross-linked to form a polyester network, poly(glycerol-dodecanoate) (PGD). Other grafted but non-cross-linked DDA molecules form semicrystalline domains, which possess a solid-liquid phase transition within the PGD matrix. The phase transition offers the resulting hybrid materials with tunable optical transparency. The PGD-DDA system shows stable performance after 100 heating-cooling cycles. In addition, when applied for window coating, it results in tough interfacial bonding to glass substrates with toughness of >6910 J m-2 below its transition temperature and >135 J m-2 above its transition temperature. It increases the impact resistance of the window by multiple times.
ABSTRACT
The thermal evolution of planetary crust and lithosphere is largely governed by the rate of heat transfer by conduction. The governing physical properties are thermal diffusivity (kappa) and conductivity (k = kapparhoC(P)), where rho denotes density and C(P) denotes specific heat capacity at constant pressure. Although for crustal rocks both kappa and k decrease above ambient temperature, most thermal models of the Earth's lithosphere assume constant values for kappa ( approximately 1 mm(2) s(-1)) and/or k ( approximately 3 to 5 W m(-1) K(-1)) owing to the large experimental uncertainties associated with conventional contact methods at high temperatures. Recent advances in laser-flash analysis permit accurate (+/-2 per cent) measurements on minerals and rocks to geologically relevant temperatures. Here we provide data from laser-flash analysis for three different crustal rock types, showing that kappa strongly decreases from 1.5-2.5 mm(2) s(-1) at ambient conditions, approaching 0.5 mm(2) s(-1) at mid-crustal temperatures. The latter value is approximately half that commonly assumed, and hot middle to lower crust is therefore a much more effective thermal insulator than previously thought. Above the quartz alpha-beta phase transition, crustal kappa is nearly independent of temperature, and similar to that of mantle materials. Calculated values of k indicate that its negative dependence on temperature is smaller than that of kappa, owing to the increase of C(P) with increasing temperature, but k also diminishes by 50 per cent from the surface to the quartz alpha-beta transition. We present models of lithospheric thermal evolution during continental collision and demonstrate that the temperature dependence of kappa and C(P) leads to positive feedback between strain heating in shear zones and more efficient thermal insulation, removing the requirement for unusually high radiogenic heat production to achieve crustal melting temperatures. Positive feedback between heating, increased thermal insulation and partial melting is predicted to occur in many tectonic settings, and in both the crust and the mantle, facilitating crustal reworking and planetary differentiation.
