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Bifunctional asymmetric catalysis: a tandem nucleophile/Lewis acid promoted synthesis of beta-lactams.
France, Stefan; Wack, Harald; Hafez, Ahmed M; Taggi, Andrew E; Witsil, Daniel R; Lectka, Thomas.
Org Lett ; 4(9): 1603-5, 2002 May 02.
Article in English | MEDLINE | ID: mdl-11975639

ABSTRACT

[reaction: see text]. We describe a superior procedure for the catalytic, asymmetric synthesis of beta-lactams using a bifunctional catalyst system consisting of a chiral nucleophile and an achiral Lewis acid.


Subject(s)
Anti-Bacterial Agents/chemical synthesis , Catalysis , Indicators and Reagents , Magnetic Resonance Spectroscopy , Metals/chemistry , Stereoisomerism , beta-Lactams
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