ABSTRACT
Applying the method for determining nitrocompounds, based on gaz chromatography technique with nitro-phosphoric detector, N-nitrosodimethylamine, N-nitrosodiethylamine, N-nitrosodibutylamine, N-nitrosotetrahydropyrrole were detected in the work environment of the plant under study (method of determining 0.2 micrograms/m3 for 1000 l/air). For qualitative purposes the data obtained were supported by mass spectrometry. Measurements of individual exposure were taken in 35 persons and stationary measurements were also applied. Among nitrosamines detected, N-nitrosodimethylamine (carcinogenic substance) occurred most commonly at working post, and its concentration was the highest (2.1-9.2 micrograms/m3).
Subject(s)
Automobiles , Carcinogens/analysis , Chemical Industry , Environmental Monitoring/methods , Nitrosamines/analysis , Occupational Exposure , Chromatography, Gas/methods , Gas Chromatography-Mass Spectrometry , Humans , RubberABSTRACT
On the basis of an external quality control of sulfur dioxide measurements in the atmospheric air (emission), the preparation of control material, its evaluation and a two-week durability of the material are presented. The results of the control test carried out in autumn 1994 is also discussed.