1.
Chem Commun (Camb)
; 59(61): 9348-9351, 2023 Jul 27.
Article
in English
| MEDLINE
| ID: mdl-37431636
ABSTRACT
We report herein the palladium-catalysed mono-selective C-H arylation of [2.2]paracyclophane (PCP) with diverse aryl iodides in the absence of any pendant directing groups, providing straightforward and modular access to C4-arylated [2.2]paracyclophanes. Moreover, a new PCP-containing biaryl monophosphine complex could be readily obtained through further derivation of the arylated product.