Unprotected Organic Cations─The Dilemma of Highly Li-Concentrated Ionic Liquid Electrolytes.

Highly Li-concentrated electrolytes have been widely studied to harness their uniquely varying bulk and interface properties that arise from their distinctive physicochemical properties and coordination structures. Similar strategies have been applied in the realm of ionic liquid electrolytes to exploit their improved functionalities. Despite these prospects, the impact of organic cation behavior on interfacial processes remains largely underexplored compared to the widely studied anion behavior. The present study demonstrates that the weakened interactions between cations and anions engender "unprotected" organic cations in highly Li-concentrated ionic liquid electrolytes, leading to the decomposition of electrolytes during the initial charge. This decomposition behavior is manifested by the substantial irreversible capacities and inferior initial Coulombic efficiencies observed during the initial charging of graphite negative electrodes, resulting in considerable electrolyte consumption and diminished energy densities in full-cell configurations. The innate cation behavior is ascertained by examining the coordination environment of ionic liquid electrolytes with varied Li concentrations, where intricate ionic interactions between organic cations and anions are unveiled. In addition, anionic species with high Lewis basicity were introduced to reinforce the ionic interactions involving organic cations and improve the initial Coulombic efficiency. This study verifies the role of unprotected organic cations while highlighting the significance of the coordination environment in the performance of ionic liquid electrolytes.

Histology and multi-omic profiling reveal the mixture toxicity of tebuconazole and difenoconazole in adult zebrafish.

The combination effects of triazole fungicides on aquatic organisms remain largely unknown. In current study, an integrated histological, transcriptome, metabonomics and microbiology was applied to investigate the mixture effects and risk of tebuconazole (TEB) and difenoconazole (DIF) co-exposure on zebrafish liver and gonad at aquatic life benchmark. TEB and DIF mixture showed additive effect on the acute toxicity to adult zebrafish, the combined toxicity on liver was less than the additive effect of individual TEB and DIF, and TEB and DIF mixture also reduced the toxic effects on gonad and intestinal microflora. Transcriptomics and metabolomics further showed TEB and DIF mixture could induce more differentially expressed genes (DEGs) to regulate the metabolic pathways involved in energy metabolism, steroid hormone biosynthesis, retinol metabolism and microbial metabolism, to balance the energy metabolism and supplies, and maintain the steroid hormone and RA level, further reduced the toxic effect on liver and gonad caused by TEB and DIF. Our results showed the different responses and patterns on transcriptional and metabolic profiles mediated in the diverse toxicity and combination effects of TEB and DIF. The present results provided a deep mechanistic understanding of the combined effects and mode of action of DIF and TEB mixture on aquatic organisms, suggesting the concept of additive effects might sufficiently protective when evaluated the combination effects and ecological risk of TEB and DIF at aquatic life benchmarks.

The Three-Dimensional Dendrite-Free Zinc Anode on a Copper Mesh with a Zinc-Oriented Polyacrylamide Electrolyte Additive.

Rechargeable aqueous zinc-ion batteries have been considered as a promising candidate for next-generation batteries. However, the formation of zinc dendrites are the most severe problems limiting their practical applications. To develop stable zinc metal anodes, a synergistic method is presented that combines the Cu-Zn solid solution interface on a copper mesh skeleton with good zinc affinity and a polyacrylamide electrolyte additive to modify the zinc anode, which can greatly reduce the overpotential of the zinc nucleation and increase the stability of zinc deposition. The as-prepared zinc anodes show a dendrite-free plating/stripping behavior over a wide range of current densities. The symmetric cell using this dendrite-free anode can be cycled for more than 280 h with a very low voltage hysteresis (93.1 mV) at a discharge depth of 80 %. The high capacity retention and low polarization are also realized in Zn/MnO2 full cells.