In Situ Growth of Highly Compatible Cu2O-GO Hybrids via Amino-Modification for Melt-Spun Efficient Antibacterial Polyamide 6 Fibers.

Polyamide 6 fiber has the advantages of high strength and good wear resistance. However, it is still challenging to effectively load inorganic antibacterial agents into polymer substrates without antimicrobial activity. In this work, graphene oxide was used as a carrier, which was modified with an aminosilane coupling agent (AEAPTMS) to enhance the compatibility and antimicrobial properties of the inorganic material, as well as to improve its thermal stability in a high-temperature melting environment. Cuprous oxide-loaded aminated grapheme (Cu2O-GO-NH2) was constructed by in situ growth method, and further PA6/Cu2O-GO-NH2 fibers were prepared by in situ polymerization. The composite fiber has excellent washing resistance. After 50 times washing, its bactericidal rates against Bacillus subtilis and Escherichia coli were 98.85% and 99.99%, respectively. In addition, the enhanced compatibility of Cu2O-GO-NH2 with the PA6 matrix improved the orientation and crystallinity of the composite fibers. Compared with PA6/Cu2O-GO fibers, the fracture strength of PA6/Cu2O-GO-NH2 fibers increased from 3.0 cN/dtex to 4.2 cN/dtex when the addition of Cu2O-GO-NH2 was 0.2 wt.%. Chemical modification and in situ concepts help to improve the compatibility of inorganic antimicrobial agents with organic polymers, which can be applied to the development of medical textiles. This article is protected by copyright. All rights reserved.

A Flexible Long-Wave Infrared Radiation Modulator Integrated with Electrochromic Behavior for Dual-Band Camouflage.

Electrochromic devices (ECDs), which are capable of modulating optical properties in the visible and long-wave infrared (LWIR) spectra under applied voltage, are of great significance for military camouflage. However, there are a few materials that can modulate dual frequency bands. In addition, the complex and specialized structural design of dual-band ECDs poses significant challenges. Here, we propose a novel approach for a bendable ECD capable of modulating LWIR radiation and displaying multiple colors. Notably, it eliminates the need for a porous electrode or a grid electrode, thereby improving both the response speed and fabrication feasibility. The device employs multiwalled carbon nanotubes (MWCNTs) as both the transparent electrode and the LWIR modulator, polyaniline (PANI) as the electrochromic layer, and ionic liquids (HMIM[TFSI]) as the electrolyte. The ECD is able to reduce its infrared emissivity (Δε = 0.23) in a short time (resulting in a drop in infrared temperature from 50 to 44 °C) within a mere duration of 0.78 ± 0.07 s while changing its color from green to yellow within 3 s when a positive voltage of 4 V is applied. In addition, it exhibits excellent flexibility, even under bending conditions. This simplified structure provides opportunities for applications such as wearable adaptive camouflage and multispectral displays.

Scalable Fabrication of Ionic-Conductive Covalent Organic Framework Fibers for Capturing of Sustainable Osmotic Energy.

High-performance covalent organic framework (COF) fibers are demanded for an efficient capturing of blue osmotic power because of their excellent durability, simple integration, and large scalability. However, the scalable production of COF fibers is still very challenging due to the poor solubility and fragile structure of COFs. Herein, for the first time, it is reported that COF dispersions can be continuously processed into macroscopic, meter-long, and pure COF fibers using a wet spinning approach. The two presented COF fibers can be directly used for capturing of osmotic energy, avoiding the production of composite materials that require other additives and face challenges such as phase separation and environmental issues induced by the additives. A COF fiber exhibits power densities of 70.2 and 185.3 W m-2 at 50-fold and 500-fold salt gradients, respectively. These values outperform those of most reported systems, which indicate the high potential of COF fibers for capturing of blue osmotic energy.

A Skin-Inspired Self-Adaptive System for Temperature Control During Dynamic Wound Healing.

The thermoregulating function of skin that is capable of maintaining body temperature within a thermostatic state is critical. However, patients suffering from skin damage are struggling with the surrounding scene and situational awareness. Here, we report an interactive self-regulation electronic system by mimicking the human thermos-reception system. The skin-inspired self-adaptive system is composed of two highly sensitive thermistors (thermal-response composite materials), and a low-power temperature control unit (Laser-induced graphene array). The biomimetic skin can realize self-adjusting in the range of 35-42 °C, which is around physiological temperature. This thermoregulation system also contributed to skin barrier formation and wound healing. Across wound models, the treatment group healed ~ 10% more rapidly compared with the control group, and showed reduced inflammation, thus enhancing skin tissue regeneration. The skin-inspired self-adaptive system holds substantial promise for next-generation robotic and medical devices.

Highly conductive and porous lignin-derived carbon fibers.

Bio-based carbon fibers derived from lignin have gained significant attention due to their diverse and renewable sources, ease of extraction, and low cost. However, the current limitations of low specific surface area and insufficient electrical conductivity hinder the widespread application of lignin-derived carbon fibers (LCFs). In this work, highly conductive and porous LCFs are developed through melt-blowing, pretreatment, and carbonization processes. The effects of the carbonization temperature and heating rate on the structures and properties of the LCFs are systematically investigated. The resultant LCFs exhibit high electrical conductivity (71 400 S m-1) and a large specific surface area (923 m2 g-1). The assembled lithium-ion battery based on the LCF anodes demonstrates a long cycle life of >800 cycles and a high specific capacity of 466 mA h g-1. The findings of this study hold practical significance for promoting the utilization of lignin in the fields of energy storage, adsorption, and beyond.

Improved Antibacterial Properties of Polylactic Acid-Based Nanofibers Loaded with ZnO-Ag Nanoparticles through Pore Engineering.

In the post-epidemic era, bio-based protective fiber materials with active protective functions are of utmost importance, not only to combat the spread of pathogens but also to reduce the environmental impact of petroleum-based protective materials. Here, efficient antibacterial polylactic acid-based (PLA-based) fibers are prepared by solution blow spinning and their pore structures are regulated by controlling the ratio of the solvent components in the spinning solutions. The porous PLA-based fibers exhibit antibacterial efficiencies of over 99% against Escherichia coli and over 98% against Bacillus subtilis, which are significantly higher than that of the nonporous PLA-based fibers. The excellent antibacterial property of the porous PLA-based fibers can be attributed to their high porosity, which allows antibacterial nanoparticles to be released more easily from the fibers, thus effectively killing pathogenic microorganisms. Moreover, pore structure regulation can also enhance the mechanical property of the PLA-based fiber materials. Our approach of regulating the microstructure and properties of the PLA-based fibers through pore engineering can be extended to other polymer fiber materials and is suitable for polymer-based composite systems that require optimal performance through sufficient exposure of doped materials.

Research progress in preparation, properties, and applications of medical protective fiber materials.

A variety of public health events seriously threaten human life and health, especially the outbreak of COVID-19 at the end of 2019 has caused a serious impact on human production and life. Wearing personal protective equipment (PPE) is one of the most effective ways to prevent infection and stop the spread of the virus. Medical protective fiber materials have become the first choice for PPE because of their excellent barrier properties and breathability. In this article, we systematically review the latest progress in preparation technologies, properties, and applications of medical protective fiber materials. We first summarize the technological characteristics of different fiber preparation methods and compare their advantages and disadvantages. Then the barrier properties, comfort, and mechanical properties of the medical protective fiber materials used in PPE are discussed. After that, the applications of medical protective fibers in PPE are introduced, and protective clothing and masks are discussed in detail. Finally, the current status, future development trend, and existing challenges of medical protective fiber materials are summarized.

Palladium Nanoparticle-Loaded Mesostructural Natural Woods for Efficient Water Treatment.

Natural wood with oriented microchannels and unique multi-level structures is an ideal candidate for making water treatment membranes. Here, palladium nanoparticles are loaded into different kinds of natural woods and the degradation property of the wood membranes for organic pollutants are investigated. The water flux of hardwoods is significantly higher than that of softwood due to the existence of large vessel elements. For the single pollutant, both hardwood and softwood show high degradation efficiency for methylene blue and methylene orange, while the degradation efficiency of the softwoods for 4-nitrophenol is significantly higher than that of the hardwoods due to their lower water flux. For the mixed pollutants, all the wood membranes have a good degradation property for different concentrations of methylene blue in polluted water, while the degradation efficiency of high concentration methylene orange and 4-nitrophenol is low. Our work will provide some guidance for the degradation of organic pollutants in actual polluted water.

Improved photocatalytic property of lignin-derived carbon nanofibers through catalyst synergy.

Converting lignin into high value-added products is essential to reduce our dependence on petroleum resources and protect our environment. In this work, TiO2 and g-C3N4 are loaded in the lignin-derived carbon nanofibers (LCNFs) and an efficient LCNFs-based photocatalytic material (TiO2/g-C3N4@LCNFs) is developed. The spinnability of lignin solution, the chemical structure and morphology of the LCNFs, and the catalytic degradation property of the TiO2/g-C3N4@LCNFs for Rhodamine B (RhB) are systematically investigated. The TiO2/g-C3N4@LCNFs achieve a 92.76 % degradation rate of RhB under UV-vis irradiation, which is close to or higher than most reported carbon fiber-based photocatalysts. The excellent degradation property of the photocatalysts can be ascribed to the synergy of TiO2 and g-C3N4, which improves the excitation efficiency of electron and hole, and prolongs the lifetime of electron-hole pairs. We envision that our work will provide some guidance for the development of efficient photocatalysts based on biomass-derived fiber materials.

The synergistic effect of heterogeneous nucleation and stress-induced crystallization on supramolecular structure and performances of poly(lactic acid) melt-spun fibers.

As a kind of bio-based polymer, poly (lactic acid) has potential application in fibers fields. Due to the weak nucleation ability, PLA crystallizes slowly and forms large spherulites during the forming process, which deteriorates the properties of PLA fibers. In this work, melt-spun method is employed for the fabrication of PLA/T composite fibers using succinate diphenyl dihydrazide (TMC-306) as the nucleating agent, and then the hot-drawing and heat setting is performed to the as-spun fibers. Compared with pure PLA fibers, PLA/T fibers show faster crystallization rate and improved performance due to the synergistic effect of heterogeneous nucleation and stress-induced crystallization. The characterization of non-isothermal crystallization behavior indicates that the peak crystallization temperature as well as crystallinity of PLA composites is increased to 121.5 °C and 36.78 % respectively by blending 0.3 wt% TMC-306. Meanwhile, the obtained PLA/0.3T composite fibers are highly crystallized and oriented at hot-drawing ratio of 2.4 folds and heat setting temperature of 100 °C, and the conformational stability is noticeably enhanced. Further, the tensile strength and storage modulus of PLA/0.3T composite fiber are 3.46 cN/dtex and 46,953 MPa respectively, which are increased by 42 % and 41 % compared with neat PLA fibers.

Piezoresistive Fibers with Large Working Factors for Strain Sensing Applications.

Piezoresistive fibers with large working factors remain of great interest for strain sensing applications involving large strains, yet difficult to achieve. Here, we produced strain-sensitive fibers with large working factors by dip-coating nanocomposite piezoresistive inks on surface-modified polyether block amide (PEBA) fibers. Surface modification of neat PEBA fibers was carried out with polydopamine (PDA) while nanocomposite conductive inks consisted of styrene-ethylene-butylene-styrene (SEBS) elastomer and carbon black (CB). As such, the deposition of piezoresistive coatings was enabled through nonconventional hydrogen-bonding interactions. The resultant fibers demonstrated well-defined piezoresistive linear relationships, which increased with CB filler loading in SEBS. In addition, gauge factors decreased with increasing CB mass fractions from ∼15 to ∼7. Furthermore, we used the fatigue theory to predict the endurance limit (Ce) of our fibers toward resistance signal stability. Such a piezoresistive performance allowed us to explore the application of our fibers as strain sensors for monitoring the movement of finger joints.

Lignin-based carbon fibers: Insight into structural evolution from lignin pretreatment, fiber forming, to pre-oxidation and carbonization.

Lignin remains the second abundant source of renewable carbon with an aromatic structure. However, most of the lignin is burnt directly for power generation, with an effective utilization rate of <2 %, making value addition on lignin an urgent requirement. From this perspective, preparation of lignin-based carbon fibers has been widely studied as an effective way to increase value addition on lignin. However, lignin species are diverse and complex in structure, and the pathway that enables changes in lignin structure during pretreatment, fiber formation, stabilization, and carbonization is still uncertain. In this review, we condense the common structural evolution route from the previous studies, which can serve as a guide towards engineered lignin carbon fibers with high performance properties.

Melt-spun bio-based PLA-co-PET copolyester fibers with tunable properties: Synergistic effects of chemical structure and drawing process.

The fabrication of bio-based copolyester fiber with adjustable crystallization, orientation structure and mechanical property still remains a great challenge. In this study, a series of copolyester fibers based on terephthalic acid (PTA), ethylene glycol (EG) and l-Lactide (L-LA) were prepared via melt copolymerization and spinning. The resultant PLA-co-PET (PETLA) fibers exhibited tunable structure and property due to the synergistic effects of chemical structure and drawing process. The chemical structure of PETLA was confirmed by NMR, FTIR and XRD, which suggested that the random degree of copolymer increased with LA content and the viscosity decreased with the increase of LA content. The crystallization behavior, melting characteristic, thermal stability and rheological property were investigated by DSC, TGA and rheometer, the results indicated that all the PETLA exhibited the crystallization capacity, melting temperature and thermal stability were slightly affected by LA segment. The synergistic effects of LA segment and spinning process on PETLA structure and property were analyzed by WAXD and SAXS. The breaking strength of PETLA fibers dropped from 5.3 cN/dtex of PET to 2.8 cN/dtex of PET85LA15, which still met the requirements of most textile applications. Therefore, our work presented a feasible approach to prepare bio-based polyester fibers with tunable property.

Continuously processing waste lignin into high-value carbon nanotube fibers.

High value utilization of renewable biomass materials is of great significance to the sustainable development of human beings. For example, because biomass contains large amounts of carbon, they are ideal candidates for the preparation of carbon nanotube fibers. However, continuous preparation of such fibers using biomass as carbon source remains a huge challenge due to the complex chemical structure of the precursors. Here, we realize continuous preparation of high-performance carbon nanotube fibers from lignin by solvent dispersion, high-temperature pyrolysis, catalytic synthesis, and assembly. The fibers exhibit a tensile strength of 1.33 GPa and an electrical conductivity of 1.19 × 105 S m-1, superior to that of most biomass-derived carbon materials to date. More importantly, we achieve continuous production rate of 120 m h-1. Our preparation method is extendable to other biomass materials and will greatly promote the high value application of biomass in a wide range of fields.

Electromechanical Performance of Strain Sensors Based on Viscoelastic Conductive Composite Polymer Fibers.

Flexible conductive polymer composite (CPC) fibers that show large changes in resistance with deformation have recently gained much attention as strain-sensing components for future wearable electronics. However, the electrical resistance of these materials decays with time during dynamic cyclic loading, a deformation performed to simulate their real application as strain sensors. Despite the extensive research on CPC fibers, the mechanism leading to this decay in the electromechanical response under repetitive cycles remains unreported. Herein, this behavior is investigated using fiber-based strain sensors wet spun from thermoplastic polyurethane (TPU) consisting of a carbonaceous hybrid conductive filler system of carbon black (CB) and carbon nanotubes (CNTs). We found electrical viscosity to predict the observed electromechanical resistance decay. This implies that cycling these materials enables the relaxation of both the polymer chains and the conductive network. In addition, the resulting piezoresistive fibers are sensitive to deformation in the region of low strain (gauge factor of 6.0 within 3.0% strain), remain conductive under 280.5% deformation, and are stable for more than 2000 cycles. Finally, we demonstrate the potential of TPU/CB-CNT fibers as strain sensors for monitoring human motion.

Effect of pre-oxidation temperature and heating rate on the microstructure of lignin carbon fibers.

Lignin is a biopolymer with high carbon content, making lignin-based carbon fiber an important research direction. In the process of carbonization to prepare carbon fibers, lignin fibers are easily softened and fused, which destroys the microstructure of fibers, thereby reducing the quality of lignin-based carbon fibers. Therefore, it is non-negligible to pre-oxidize lignin fibers before carbonization to prevent fiber fusion and maintain fiber structure. Therefore, the effects of pre-oxidation temperature and heating rate on the structure of pre-oxidation lignin fibers with controllable diameter and thickness prepared by melt-blowing were studied in detail. During pre-oxidation, crosslinking and aromatization of lignin fibers occurred, and alkyl and benzene rings were mainly oxidized to form carbonyl groups. The aromatization degree of the pre-oxidized product was recorded at 280 °C and 0.25 °C/min, and the oxygen content reached 15 %-20 %, making it suitable for the preparation of bio-based carbon fibers. On this basis, carbon fibers with porous morphology can be prepared with a graphitization of 0.54 and a resistivity of 0.02 Ω cm-1. These materials are expected to be applicable in sensors, catalytic materials and other fields.

Flexible Ceramic Fibers: Recent Development in Preparation and Application.

Flexible ceramic fibers (FCFs) have been developed for various advanced applications due to their superior mechanical flexibility, high temperature resistance, and excellent chemical stability. In this article, we present an overview on the recent progress of FCFs in terms of materials, fabrication methods, and applications. We begin with a brief introduction to FCFs and the materials for preparation of FCFs. After that, various methods for preparation of FCFs are discussed, including centrifugal spinning, electrospinning, solution blow spinning, self-assembly, chemical vapor deposition, atomic layer deposition, and polymer conversion. Recent applications of FCFs in various fields are further illustrated in detail, including thermal insulation, air filtration, water treatment, sound absorption, electromagnetic wave absorption, battery separator, catalytic application, among others. Finally, some perspectives on the future directions and opportunities for the preparation and application of FCFs are highlighted. We envision that this review will provide readers with some meaningful guidance on the preparation of FCFs and inspire them to explore more potential applications.

Solid-state intramolecular motions in continuous fibers driven by ambient humidity for fluorescent sensors.

One striking feature of molecular rotors is their ability to change conformation with detectable optical signals through molecular motion when stimulated. However, due to the strong intermolecular interactions, synthetic molecular rotors have often relied on fluid environments. Here, we take advantage of the solid-state intramolecular motion of aggregation-induced emission (AIE) molecular rotors and one-dimensional fibers, developing highly sensitive optical fiber sensors that respond to ambient humidity rapidly and reversibly with observable chromatic fluorescence change. Moisture environments induce the swelling of the polymer fibers, activating intramolecular motions of AIE molecules to result in red-shifted fluorescence and linear response to ambient humidity. In this case, polymer fiber provides a process-friendly architecture and a physically tunable medium for the embedded AIE molecules to manipulate their fluorescence response characteristics. Assembly of sensor fibers could be built into hierarchical structures, which are adaptive to diverse-configuration for spatial-temporal humidity mapping, and suitable for device integration to build light-emitting sensors as well as touchless positioning interfaces for intelligence systems.

Effective and biocompatible antibacterial surfaces via facile synthesis and surface modification of peptide polymers.

It is an urgent need to tackle drug-resistance microbial infections that are associated with implantable biomedical devices. Host defense peptide-mimicking polymers have been actively explored in recent years to fight against drug-resistant microbes. Our recent report on lithium hexamethyldisilazide-initiated superfast polymerization on amino acid N-carboxyanhydrides enables the quick synthesis of host defense peptide-mimicking peptide polymers. Here we reported a facile and cost-effective thermoplastic polyurethane (TPU) surface modification of peptide polymer (DLL: BLG = 90 : 10) using plasma surface activation and substitution reaction between thiol and bromide groups. The peptide polymer-modified TPU surfaces exhibited board-spectrum antibacterial property as well as effective contact-killing ability in vitro. Furthermore, the peptide polymer-modified TPU surfaces showed excellent biocompatibility, displaying no hemolysis and cytotoxicity. In vivo study using methicillin-resistant Staphylococcus aureus (MRSA) for subcutaneous implantation infectious model showed that peptide polymer-modified TPU surfaces revealed obvious suppression of infection and great histocompatibility, compared to bare TPU surfaces. We further explored the antimicrobial mechanism of the peptide polymer-modified TPU surfaces, which revealed a surface contact-killing mechanism by disrupting the bacterial membrane. These results demonstrated great potential of the peptide-modified TPU surfaces for practical application to combat bacterial infections that are associated with implantable materials and devices.

Smart fibers for energy conversion and storage.

Fibers have played a critical role in the long history of human development. They are the basic building blocks of textiles. Synthetic fibers not only make clothes stronger and more durable, but are also customizable and cheaper. The growth of miniature and wearable electronics has promoted the development of smart and multifunctional fibers. Particularly, the incorporation of functional semiconductors and electroactive materials in fibers has opened up the field of fiber electronics. The energy supply system is the key branch for fiber electronics. Herein, after a brief introduction on the history of smart and functional fibers, we review the current state of advanced functional fibers for their application in energy conversion and storage, focusing on nanogenerators, solar cells, supercapacitors and batteries. Subsequently, the importance of the integration of fiber-shaped energy conversion and storage devices via smart structure design is discussed. Finally, the challenges and future direction in this field are highlighted. Through this review, we hope to inspire scientists with different research backgrounds to enter this multi-disciplinary field to promote its prosperity and development and usher in a truly new era of smart fibers.