[Research on the near-infrared spectrometer system].

Near-infrared spectrometer is the integration of spectrum test technology, stoichiometry technology and computer technology. In the present paper, based on effective food ingredients and non-invasive quantitative detection, the development process of the micro-near-infrared spectrometer system was introduced. Spectrometer is the basis of the system. This paper focuses on the development of the micro-near-infrared spectrometer applicable to on-line real-time testing. A micro-near-infrared spectrometer prototype was developed successfully, its main technical parameter was tested, and the result shows: its operating wavelength is: 850-1 690 nm, optical resolution is: less than 10 nm, and its performance has achieved the level of the congener foreign products. Stoichiometric technology and computer technology is the core of the system. LS-LWR modeling methods were proposed. Finally, the quantitative test for glucose water solution using the micro-near-infrared spectrometer shows that the correlation coefficient of prediction model is 0.995, and the corresponding RMSEP is 0.06.

[Design and simulation of the NIR micro-spectrometer optical system].

Based on the working principle of analyzing spectrometer and the theory of optical design, to make the system miniature, and with a certain spectral range and resolution requirements as specific design objectives, a cross-C-T micro-structure based on a plane diffraction grating spectrophotometer of the near-infrared spectrometer was put forward; ZEMAX was used for design and optimizing and simulating analysis of micro-near-infrared spectrometer in the optical system. The result showed that the micro-optical system's spectral range was 900-1 700 nm, resolution was < 10 nm, spectrum broadening was 12.74 mm, F number was 8.128 388, and the system volume was 51.26 mmX41.81 mmX22 mm, and these all satisfy the requirements. It solved the micromation of the optical system of the spectrometer, and therefore, contributed to the micromation of the spectrometer itself.

[Design of flat field holographic concave grating for near-infrared spectrophotometer].

Near-infrared spectrum analysis can be used to determine the nature or test quantitatively some chemical compositions by detecting molecular double frequency and multiple frequency absorption. It has been used in agriculture, biology, petrifaction, foodstuff, medicament, spinning and other fields. Near-infrared spectrophotometer is the main apparatus for near-infrared spectrum analysis, and the grating is the most important part of the apparatus. Based on holographic concave grating theory and optic design software CODE V, a flat field holographic concave grating for near-infrared spectrophotometer was designed from primary structure, which relied on global optimization of the software. The contradiction between wide spectrum bound and limited spectrum extension was resolved, aberrations were reduced successfully, spectrum information was utilized fully, and the optic structure of spectrometer was highly efficient. Using CODE V software, complex high-order aberration equations need not be solved, the result can be evaluated quickly, flat field and resolving power can be kept in balance, and the work efficiency is also enhanced. A paradigm of flat field holographic concave grating is given, it works between 900 nm to 1 700 nm, the diameter of the concave grating is 25 mm, and F/ # is 1. 5. The design result was analyzed and evaluated. It was showed that if the slit source, whose width is 50 microm, is used to reconstruction, the theoretic resolution capacity is better than 6.3 nm.

[Development of a micro-infrared spectrometer based on pulse infrared light source and two-double light route].

A novel micro infrared spectrometer was designed which is different from traditional grating scanning one. This micro spectrometer introduced an uncooled infrared detector LiTaO3 with high sensitivity and small volume, and a MEMS pulsed infrared light source was adopted as emitter and chopper, which threw off traditional mechanical chopper. Combined with the design of a two-double light route, the volume of micro spectrometer was made even smaller. Primary results show that the design method of micro-infrared spectrometer is feasible, the wavelength range of instrument is wide, from 2000 to 5000 nm, and spectrum bandwidth is about 45 nm, which can be used for the sample analysis, such as plastic films, biologic liquid, environmental gas and so on.

[Model transfer method based on support vector machine].

The model transfer is a basic method to build up universal and comparable performance of spectrometer data by seeking a mathematical transformation relation among different spectrometers. Because of nonlinear effect and small calibration sample set in fact, it is important to solve the problem of model transfer under the condition of nonlinear effect in evidence and small sample set. This paper summarizes support vector machines theory, puts forward the method of model transfer based on support vector machine and piecewise direct standardization, and makes use of computer simulation method, giving a example to explain the method and compare it with artificial neural network in the end.