ABSTRACT
Three-dimensional (3D) confocal x-ray fluorescence analysis technology is widely used, but the quantitative analysis of elemental spatial distributions of solid samples is complicated. This paper explores a quantitative analysis method that can be applied to solid samples. Fluorescence spectra of liquid samples are obtained on a 3D confocal x-ray fluorescence spectrometer. Curves are plotted showing the relationships between the fluorescence count intensity and the mass percentage of metal ions, and the respective fitting-curve equations are determined according to the curve morphology. Fluorescence intensity as a function of the mass percentage and depth position is derived from the samples for a particular acquisition time. These data play a potential role in the subsequent quantitative analysis of unknown mass percentages of solid samples.
ABSTRACT
Three-dimensional microfocus x-ray fluorescence technology has been used to determine surface topography. The surface scanning technique initially facilitated surface topography reconstruction of the sample. This paper demonstrates the improved performance of its infrastructure, including a higher-precision translation platform, an ultrabright microfocus x-ray source and a rewritten scanning algorithm, leading to a new scanning technology that can depict the surface topography of samples with complex internal structures. The improved scanning technology can analyze the metal element information of layers at different depths. This paper presents studies of the surface and depth of coins and porcelain bottles from ancient times using this technique.
