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J Mater Sci Mater Med ; 19(1): 175-82, 2008 Jan.
Article in English | MEDLINE | ID: mdl-17597359

ABSTRACT

Silicon Substituted Hydroxyapatite (Si-HA) coatings were prepared on titanium substrates by electrophoretic deposition (EPD). The stability of Si-HA suspension in n-butanol and chloroform mixture has been studied by electricity conductivity and sedimentation test. The microstructure, shear strength and bioactivity in vitro has been tested. The stability of Si-HA suspension containing n-butanol and chloroform mixture as medium is better than that of pure n-butanol as medium. The good adhesion of the particles with the substrate and good cohesion between the particles were obtained in n-butanol and chloroform mixture. Adding triethanolamine (TEA) as additive into the suspension is in favor of the formation of uniform and compact Si-HA coatings on the titanium substrates by EPD. The shear strength of the coatings can reach 20.43 MPa after sintering at 700 degrees C for 2 h, when the volume ratio of n-butanol: chloroform is 2:1 and the concentration of TEA is 15 ml/L. Titanium substrates etched in H(2)O(2)/NH(3) solution help to improve the shear strength of the coatings. After immersion in simulated body fluid for 7 days, Si-HA coatings have the ability to induce the bone-like apatite formation.


Subject(s)
1-Butanol/chemistry , Chloroform/chemistry , Durapatite/chemistry , Electrophoresis/methods , Ethanolamines/chemistry , Silicon/chemistry , Body Fluids , Microscopy, Electron, Transmission , Models, Chemical , Powders , Pressure , Stress, Mechanical , Temperature , Time Factors , X-Ray Diffraction
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