Targeted degradation of TBBPA using novel molecularly imprinted polymer encapsulated C-Fe-Nx nanocomposite driven from MOFs.

To improve the efficacy of organic pollutant removal using sulfate radicals, we designed MIP@C-Fe-Nx, a molecularly imprinted material capable of targeting the degradation of tetrabromobisphenol A (TBBPA), which can be used as both adsorbent and catalyst to recognize and degrade Tetrabromobisphenol A (TBBPA) accurately, and the final removal rate of TBBPA can reach 104.6 mg·g-1. Based on the synergistic effects of MIP@C-Fe-Nx on the excellent organic pollutant recognition and catalytic performance, low concentrations of TBBPA can be pre-targeted, concentrated, and fixed on the surface of MIP, and degraded simultaneously in-situ by·OH and SO4•- which are produced by activating PS with C-Fe-Nx. Recognition experiments demonstrated that MIPs had perfect performance in recognizing and adsorbing TBBPA and debromination intermediates. The DFT calculations and HPLC-MS analysis indicated that MIP@C-Fe-Nx had a targeted recognition and accumulation for TBBPA and debromination intermediates, for example, dibromobisphenol A, monobromobisphenol A, and bisphenol A, thus avoid the formation of toxic intermediates causing secondary contamination.

Occurrence and risk assessment of antibiotics in multifunctional reservoirs in Dongguan, China.

It is necessary to study the contamination of antibiotics in natural water bodies and assess its impact on ecological and human risks because of the large-scale use in the world. The occurrence and distribution characteristics of 45 antibiotics in reservoirs in Dongguan were investigated. Approximately, 77.8% of the detectable concentration of 35 antibiotics were found in the evaluation samples with concentration ranged from not detected (ND) to 729.59 ng/L, and dehydrated erythromycin was the highest one that appeared in Tongsha Reservoir. Fluoroquinolones and tetracyclines were the most abundant antibiotics with the detection frequency of 100% at sum concentration of 7.23-212.43 ng/L and 13.46-72.66 ng/L, respectively. Macrolides had a lower detected frequency but with highest concentration level at five kinds of antibiotics. Sulfamethoxazole, lincomycin, dehydrated erythromycin, pefloxacin, and panofloxacin were selected as important evaluation indicators. Sulfaguanidine, sulfamethoxazole, sulfisoxazole, dehydrated erythromycin, and clarithromycin that showed a significant correlation with Cl- and SO42- indicated that the pollution source of these antibiotics may be related to wastewater treatment plants. Among detected antibiotics, trimethoprim, norfloxacin, sarafloxacin, lincomycin, oxytetracycline, novobiocin, dehydrated erythromycin, and clarithromycin presented high risk to aquatic ecosystem in the reservoirs. There was no risk to humans at different ages of detected antibiotics, but it should attract attention because of the cumulative effects of antibiotics, which may cause potential risks to the human body.